HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. What is the chemical reaction that involves breaking down a compound into component parts?
- A. Decomposition
- B. Synthesis
- C. Combustion
- D. Single replacement
Correct answer: A
Rationale: Decomposition is the correct answer because in a decomposition reaction, a compound is broken down into simpler substances. This type of reaction involves the splitting of a compound into its component parts, often through the use of heat, light, or electricity. Synthesis (choice B) is the opposite process where simpler substances are combined to form a more complex compound. Combustion (choice C) is a reaction involving rapid oxidation often accompanied by heat and light. Single replacement (choice D) is a reaction where one element replaces another in a compound.
3. What is another name for aqueous HI?
- A. hydroiodic acid
- B. hydrogen monoiodide
- C. hydrogen iodide
- D. hydriodic acid
Correct answer: D
Rationale: The correct name for aqueous HI is 'hydriodic acid.' When hydrogen iodide (HI) dissolves in water, it forms hydriodic acid. Therefore, 'hydriodic acid' is the appropriate term for aqueous HI. Choice A, 'hydroiodic acid,' is incorrect as it does not reflect the nature of the compound in the aqueous state. Choice B, 'hydrogen monoiodide,' is not a widely recognized term for this compound. Choice C, 'hydrogen iodide,' is the name for HI in the gaseous state, not when it's dissolved in water.
4. How are elements arranged in the periodic table?
- A. By their atomic mass
- B. By their chemical properties
- C. By their physical state
- D. By their charge
Correct answer: B
Rationale: Elements are arranged in the periodic table based on their chemical properties, making choice B the correct answer. The periodic table is organized so that elements with similar chemical properties are grouped together in columns, known as groups or families. This arrangement allows for the identification of trends in the behavior of elements and predicting their properties based on their position in the table. Choices A, C, and D are incorrect because the periodic table primarily focuses on the chemical properties of elements, not solely on atomic mass, physical state, or charge.
5. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
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