which of these intermolecular forces would have the lowest boiling point
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HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. Which type of chemical bond is the strongest?

Correct answer: C

Rationale: Covalent bonds, especially those formed between non-metals, are the strongest type of chemical bond. In covalent bonds, atoms share electrons, creating a strong bond that requires a significant amount of energy to break. Choice A, ionic bonds, are strong but generally weaker than covalent bonds as they involve the transfer of electrons rather than sharing. Choice B, hydrogen bonds, are relatively weak intermolecular forces, not true chemical bonds. Choice D, metallic bonds, are strong but typically not as strong as covalent bonds. Metallic bonds involve a 'sea of electrons' shared between metal atoms, providing strength but with less directional bonding compared to covalent bonds.

3. To the nearest whole number, what is the mass of one mole of hydrogen iodide?

Correct answer: C

Rationale: The molar mass of hydrogen iodide (HI) is the sum of the atomic masses of its constituent elements. Hydrogen (H) has a molar mass of approximately 1 g/mol, and iodine (I) has a molar mass of about 127 g/mol. Thus, the molar mass of hydrogen iodide (HI) is approximately 1 + 127 = 128 g/mol. Rounding to the nearest whole number, the molar mass of hydrogen iodide is 128 g/mol, which is closest to choice C. Choice A (2 g/mol) is too low and does not reflect the correct molar mass of hydrogen iodide. Choice B (58 g/mol) is significantly lower than the actual molar mass. Choice D (128 g/mol) matches the calculated molar mass but is not the nearest whole number as requested.

4. What are the products of combustion of a hydrocarbon in excess oxygen?

Correct answer: A

Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.

5. Which state of matter has a definite volume but takes the shape of its container?

Correct answer: B

Rationale: The state of matter that has a definite volume but takes the shape of its container is a 'Liquid.' Liquids have a fixed volume but can change their shape to fit the container they are in. This property distinguishes liquids from solids, which have both a definite shape and volume, and gases, which do not have a fixed volume or shape. Therefore, the correct answer is 'Liquid.' Choice A, 'Gas,' is incorrect because gases do not have a definite volume or shape. Choice C, 'Solid,' is incorrect as solids have a definite shape and volume. Choice D, 'Plasma,' is incorrect because plasma is a state of matter where atoms have been ionized and do not have a fixed volume or shape.

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