HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
3. Carbon-12 and carbon-14 are isotopes. What do they have in common?
- A. Number of nuclear particles
- B. Number of protons
- C. Number of neutrons
- D. Mass number
Correct answer: C
Rationale: Isotopes are atoms of the same element with the same number of protons (which determines the element) but different numbers of neutrons. Both carbon-12 and carbon-14 have 6 protons (hence they are both carbon atoms) but different numbers of neutrons: carbon-12 has 6 neutrons, while carbon-14 has 8 neutrons. Therefore, the correct answer is the number of neutrons. Choices A, B, and D are incorrect because isotopes may have different numbers of nuclear particles (protons + neutrons), protons, and mass numbers, respectively.
4. Which of these elements has the greatest atomic mass?
- A. Au
- B. Ba
- C. I
- D. W
Correct answer: D
Rationale: Among the elements listed, Tungsten (W) has the greatest atomic mass. The atomic mass of Tungsten is approximately 183.84 atomic mass units (amu), while the atomic masses of the other elements listed are as follows: Gold (Au) is around 196.97 amu, Barium (Ba) is approximately 137.33 amu, and Iodine (I) is about 126.90 amu. Therefore, Tungsten (W) has the greatest atomic mass out of the given elements. Gold (Au) has a higher atomic mass than Barium (Ba) and Iodine (I), making choices A, B, and C incorrect.
5. What can stop the penetration of gamma radiation?
- A. Aluminum foil
- B. Glass
- C. Several feet of concrete
- D. Piece of paper
Correct answer: C
Rationale: Gamma radiation is highly penetrative and requires dense materials to block it effectively. While aluminum foil and glass are not sufficient to stop gamma radiation, several feet of concrete is needed due to its high density and ability to absorb gamma radiation effectively. A piece of paper is too thin and lacks the density required to block gamma radiation, making it an ineffective shield.
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