which of these intermolecular forces would have the lowest boiling point
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HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. What is the process of breaking bonds and forming new bonds to create new chemical compounds?

Correct answer: B

Rationale: A chemical reaction involves the breaking and forming of bonds to create new substances. During a chemical reaction, the original chemical bonds are broken, and new bonds are formed to produce one or more new substances with different properties from the reactants. This transformation is a fundamental concept in chemistry and distinguishes chemical reactions from physical, nuclear, or mechanical reactions. Choice A, 'Physical reaction,' does not involve the breaking and forming of chemical bonds but rather changes in physical state or appearance. Choice C, 'Nuclear reaction,' involves changes in the nuclei of atoms, not the breaking and forming of chemical bonds. Choice D, 'Mechanical reaction,' refers to reactions involving physical forces or movements, not the breaking and forming of chemical bonds as in a chemical reaction.

3. Which compound contains a polar covalent bond?

Correct answer: D

Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.

4. What is the name of the negatively charged subatomic particles?

Correct answer: C

Rationale: The correct answer is C: Electrons. Electrons are the negatively charged subatomic particles. They are found outside the atomic nucleus and carry a negative charge. Protons are positively charged particles found in the nucleus, neutrons have no charge, and isotopes are atoms of the same element with different numbers of neutrons, not subatomic particles.

5. Which two elements are most alike in reactivity?

Correct answer: C

Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.

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