HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. How can water be boiled at room temperature?
- A. By lowering the pressure
- B. By increasing the pressure
- C. By decreasing the volume
- D. By raising the boiling point
Correct answer: A
Rationale: The boiling point of water is directly affected by pressure. By lowering the pressure, water can boil at a lower temperature, even at room temperature. This occurs because at lower pressures, the molecules of water have less resistance to escaping into the vapor phase, thus enabling boiling to occur at lower temperatures. Choices B, C, and D are incorrect because increasing the pressure, decreasing the volume, or raising the boiling point would actually require higher temperatures to boil water rather than achieving boiling at room temperature.
3. In what type of covalent compounds are dispersion forces typically found?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces that occur in non-polar covalent compounds. These forces result from temporary shifts in electron density within molecules, creating temporary dipoles. As a result, non-polar molecules, which lack a permanent dipole moment, can experience these dispersion forces. Polar compounds exhibit stronger intermolecular forces such as dipole-dipole interactions or hydrogen bonding, while ionic compounds involve electrostatic interactions between ions. Therefore, the correct answer is non-polar (choice B). Choices A, C, and D are incorrect because dispersion forces are typically found in non-polar covalent compounds, not polar, ionic, or hydrogen-bonded compounds.
4. What are positively charged ions called?
- A. Neutrons
- B. Protons
- C. Cations
- D. Electrons
Correct answer: C
Rationale: Positively charged ions are called cations. When an atom loses electrons, it becomes positively charged and is referred to as a cation. Neutrons are neutral particles found in the nucleus of an atom, not charged. Protons are positively charged particles in the nucleus. Electrons are negatively charged particles orbiting the nucleus, not positively charged ions.
5. What type of chemical reaction involves the reaction of a compound with oxygen?
- A. Decomposition
- B. Synthesis
- C. Combustion
- D. Single replacement
Correct answer: C
Rationale: The correct answer is C: Combustion. A combustion reaction is characterized by a compound reacting with oxygen. During this process, heat and light are often produced as energy is released in the form of heat. Combustion is a common type of reaction involving organic compounds, like hydrocarbons, reacting with oxygen to produce carbon dioxide and water. Choices A, B, and D are incorrect because decomposition involves a compound breaking down into simpler substances, synthesis involves the combination of two or more substances to form a more complex one, and single replacement involves an element replacing another element in a compound.
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