which of these intermolecular forces would have the lowest boiling point
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HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. What is the oxidation state of the oxygen atom in the compound NaOH?

Correct answer: B

Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.

3. What type of chemical reaction involves the reaction of a compound with oxygen?

Correct answer: C

Rationale: The correct answer is C: Combustion. A combustion reaction is characterized by a compound reacting with oxygen. During this process, heat and light are often produced as energy is released in the form of heat. Combustion is a common type of reaction involving organic compounds, like hydrocarbons, reacting with oxygen to produce carbon dioxide and water. Choices A, B, and D are incorrect because decomposition involves a compound breaking down into simpler substances, synthesis involves the combination of two or more substances to form a more complex one, and single replacement involves an element replacing another element in a compound.

4. What is the name of the compound CH₃-CH₂-CH₂-CH₃?

Correct answer: B

Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.

5. What is the number of protons in the atomic nucleus of an alkali metal?

Correct answer: C

Rationale: The number of protons in the atomic nucleus of an alkali metal is 11. Alkali metals, belonging to group 1 of the periodic table, have 1 electron in their outer shell, which corresponds to 1 proton in their nucleus. Therefore, the correct answer is option C: 11. Choice A (9) is incorrect because it does not match the number of protons in an alkali metal. Choice B (10) is incorrect as it is also not the correct number of protons for an alkali metal. Choice D (12) is incorrect as it is not the typical number of protons found in the nucleus of an alkali metal.

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