HESI A2
Chemistry Hesi A2
1. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?
- A. Carbon monoxide
- B. Helium
- C. Nitrogen
- D. Oxygen
Correct answer: B
Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.
2. Which is a triatomic allotrope of oxygen?
- A. Ozone
- B. Water
- C. Acidic oxide
- D. Carbon dioxide
Correct answer: A
Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.
3. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
4. To the nearest whole number, what is the mass of one mole of hydrogen chloride?
- A. 36 g/mol
- B. 38 g/mol
- C. 71 g/mol
- D. 74 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen chloride (HCl) is calculated by adding the atomic masses of hydrogen (H) and chlorine (Cl) together. The atomic mass of hydrogen is approximately 1 g/mol, and the atomic mass of chlorine is approximately 35.5 g/mol. Therefore, the molar mass of hydrogen chloride (HCl) is approximately 1 + 35.5 = 36.5 g/mol. When rounded to the nearest whole number, it is 36 g/mol. Therefore, the correct answer is 36 g/mol. Choices A, B, and D are incorrect as they do not reflect the accurate molar mass of hydrogen chloride.
5. Balance this equation: Zn + HCl → ZnCl + H2.
- A. Zn + 2HCl → ZnCl + H2
- B. Zn + HCl → 2ZnCl + H2
- C. 2Zn + 2HCl → 2ZnCl + H2
- D. Zn + 4HCl → ZnCl + H2
Correct answer: C
Rationale: The given unbalanced equation is Zn + HCl → ZnCl + H2. To balance it, we need to have equal atoms on both sides of the equation. The balanced equation is 2Zn + 2HCl → 2ZnCl + H2. This balanced equation shows that two atoms of Zn combine with two molecules of HCl to form two molecules of ZnCl and one molecule of H2. Choice A is incorrect because it does not balance the equation. Choice B is incorrect as it does not have the same number of atoms on both sides. Choice D is incorrect because it does not balance the equation properly, resulting in an unequal number of atoms on both sides.
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