HESI A2
Chemistry Hesi A2
1. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
2. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?
- A. 0.04 M NaCl
- B. 0.25 M NaCl
- C. 0.40 M NaCl
- D. 2.5 M NaCl
Correct answer: C
Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.
3. How many electrons are in a neutral atom of neon?
- A. 9
- B. 10
- C. 11
- D. 12
Correct answer: B
Rationale: The atomic number of neon is 10, which represents the number of protons in its nucleus. In a neutral atom, the number of electrons is equal to the number of protons to maintain electrical neutrality. Therefore, a neutral atom of neon contains 10 electrons, matching the 10 protons within the nucleus. Choice A (9 electrons) is incorrect as it doesn't correspond to the atomic number of neon. Choices C (11 electrons) and D (12 electrons) are also incorrect as they do not align with the correct atomic number of neon.
4. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
- A. 16
- B. 13
- C. 10
- D. 3
Correct answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
5. Identify the type of reaction shown: 8Fe + S → 8FeS
- A. Single displacement
- B. Double displacement
- C. Synthesis
- D. Acid-base
Correct answer: C
Rationale: The reaction shown (8Fe + S → 8FeS) is a synthesis reaction. In a synthesis reaction, two or more substances combine to form a single compound. In this case, iron (Fe) and sulfur (S) combine to form iron sulfide (FeS). The key characteristic of a synthesis reaction is the formation of a single product from multiple reactants, which aligns with the given chemical equation. Choice A, single displacement, involves an element displacing another in a compound, which is not the case here. Choice B, double displacement, involves the exchange of ions between two compounds, which is also not happening in this reaction. Choice D, acid-base, refers to reactions between an acid and a base to form salt and water, which is not the case in the given equation.
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