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HESI A2

Chemistry Hesi A2

1. Identify the type of reaction shown: 8Fe + S → 8FeS

Correct answer: C

Rationale: The reaction shown (8Fe + S → 8FeS) is a synthesis reaction. In a synthesis reaction, two or more substances combine to form a single compound. In this case, iron (Fe) and sulfur (S) combine to form iron sulfide (FeS). The key characteristic of a synthesis reaction is the formation of a single product from multiple reactants, which aligns with the given chemical equation. Choice A, single displacement, involves an element displacing another in a compound, which is not the case here. Choice B, double displacement, involves the exchange of ions between two compounds, which is also not happening in this reaction. Choice D, acid-base, refers to reactions between an acid and a base to form salt and water, which is not the case in the given equation.

2. What are the products of combustion of a hydrocarbon in excess oxygen?

Correct answer: A

Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.

3. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?

Correct answer: B

Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.

4. Which is a triatomic allotrope of oxygen?

Correct answer: A

Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.

5. Which compound has a nonpolar bond in which the electrons are shared equally?

Correct answer: D

Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.

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