HESI A2
Chemistry Hesi A2
1. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
2. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
3. What does a blood sample with a pH of 3 indicate?
- A. It is strongly acidic.
- B. It is strongly basic.
- C. It is weakly acidic.
- D. It is weakly basic.
Correct answer: A
Rationale: A blood pH of 3 is significantly low, indicating a strong acidity level. The normal blood pH range is 7.35 to 7.45; therefore, a pH of 3 is far below the normal range, showing a highly acidic condition in the blood sample. Choice B is incorrect because a pH of 3 is not basic at all. Choice C is incorrect as a pH of 3 is not weakly acidic but strongly acidic. Choice D is wrong as a blood pH of 3 does not indicate a weakly basic condition.
4. What is the correct name of MgO?
- A. Manganese oxide
- B. Magnesium oxide
- C. Magnesium oxate
- D. Magnesium hydroxide
Correct answer: B
Rationale: The correct name of MgO is Magnesium oxide. Mg represents the chemical symbol for magnesium, and O represents the chemical symbol for oxygen. When these elements combine, they form magnesium oxide. Option A, Manganese oxide, is incorrect as it refers to a compound of manganese and oxygen, not magnesium. Option C, Magnesium oxate, is not a valid chemical compound name. Option D, Magnesium hydroxide, refers to a different compound consisting of magnesium, oxygen, and hydrogen.
5. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
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