HESI A2
Chemistry Hesi A2
1. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
2. Balance this equation: Zn + HCl → ZnCl + H2.
- A. Zn + 2HCl → ZnCl + H2
- B. Zn + HCl → 2ZnCl + H2
- C. 2Zn + 2HCl → 2ZnCl + H2
- D. Zn + 4HCl → ZnCl + H2
Correct answer: C
Rationale: The given unbalanced equation is Zn + HCl → ZnCl + H2. To balance it, we need to have equal atoms on both sides of the equation. The balanced equation is 2Zn + 2HCl → 2ZnCl + H2. This balanced equation shows that two atoms of Zn combine with two molecules of HCl to form two molecules of ZnCl and one molecule of H2. Choice A is incorrect because it does not balance the equation. Choice B is incorrect as it does not have the same number of atoms on both sides. Choice D is incorrect because it does not balance the equation properly, resulting in an unequal number of atoms on both sides.
3. What are the products of combustion of a hydrocarbon in excess oxygen?
- A. Carbon dioxide and water
- B. Naphthalene
- C. Chlorine and bromine
- D. Carbonium ions
Correct answer: A
Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.
4. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
5. In the solid state, you would expect a nonmetal to be _________.
- A. brittle
- B. lustrous
- C. malleable
- D. conductive
Correct answer: A
Rationale: In the solid state, you would expect a nonmetal to be brittle. Nonmetals generally lack the malleability and ductility of metals, which makes them prone to being brittle and easily fractured under stress. This property is due to the lack of metallic bonding in nonmetals, which results in a more rigid and less flexible structure. Choice B, 'lustrous,' is incorrect because nonmetals typically do not exhibit a shiny or reflective surface like metals do. Choice C, 'malleable,' is also incorrect as nonmetals lack the ability to be hammered or rolled into thin sheets like metals. Choice D, 'conductive,' is incorrect since nonmetals are generally poor conductors of electricity compared to metals.
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