HESI A2
Chemistry Hesi A2
1. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
2. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
- A. 16
- B. 13
- C. 10
- D. 3
Correct answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
3. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
4. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
5. Which substance causes a drop to rapidly turn litmus dye from blue to red?
- A. Milk
- B. Sea water
- C. Ammonia
- D. Lemon juice
Correct answer: D
Rationale: Lemon juice is the correct answer as it is acidic in nature. Acids like lemon juice release hydrogen ions when dissolved in water, which causes litmus dye to change color from blue to red. Milk (Choice A) is neutral, sea water (Choice B) is slightly alkaline, and ammonia (Choice C) is a base. Therefore, these substances do not cause litmus dye to change from blue to red.
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