HESI A2
Chemistry Hesi A2
1. To the nearest whole number, what is the mass of one mole of hydrogen chloride?
- A. 36 g/mol
- B. 38 g/mol
- C. 71 g/mol
- D. 74 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen chloride (HCl) is calculated by adding the atomic masses of hydrogen (H) and chlorine (Cl) together. The atomic mass of hydrogen is approximately 1 g/mol, and the atomic mass of chlorine is approximately 35.5 g/mol. Therefore, the molar mass of hydrogen chloride (HCl) is approximately 1 + 35.5 = 36.5 g/mol. When rounded to the nearest whole number, it is 36 g/mol. Therefore, the correct answer is 36 g/mol. Choices A, B, and D are incorrect as they do not reflect the accurate molar mass of hydrogen chloride.
2. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
3. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
4. Which is a triatomic allotrope of oxygen?
- A. Ozone
- B. Water
- C. Acidic oxide
- D. Carbon dioxide
Correct answer: A
Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.
5. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
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