HESI A2
HESI A2 Chemistry Practice Questions
1. Which of these represents a strong acid?
- A. CH₃COOH
- B. H₂SO₄
- C. NH₃
- D. KOH
Correct answer: B
Rationale: Among the options provided, H₂SO₄ (sulfuric acid) represents a strong acid. Strong acids completely ionize in water to produce a high concentration of H+ ions. Sulfuric acid is a strong acid known for its ability to dissociate almost completely in water, making it a strong acid. Choice A, CH₃COOH (acetic acid), is a weak acid that only partially dissociates in water. Choices C and D, NH₃ (ammonia) and KOH (potassium hydroxide), are bases and not acids.
2. What distinguishes one allotrope from another?
- A. Arrangement of atoms
- B. Gram atomic mass
- C. Physical state
- D. Stability
Correct answer: A
Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.
3. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
4. What is the correct electron configuration for nitrogen?
- A. 1s² 2s²
- B. 1s² 2s² 2p²
- C. 1s² 2s² 2p³
- D. 1s² 2s² 2p⁴
Correct answer: C
Rationale: The electron configuration of nitrogen is determined by its atomic number, which is 7. Nitrogen has 7 electrons. Following the order of filling orbitals, the electron configuration for nitrogen is 1s² 2s² 2p³. This means the first energy level is filled with 2 electrons in the 1s orbital, the second energy level is filled with 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. Each orbital can hold a specific number of electrons, and nitrogen, with its 7 electrons, fits this configuration. Choice A is incorrect because it does not account for all the electrons in the nitrogen atom. Choice B is incorrect as it only represents 6 electrons, not the 7 electrons in nitrogen. Choice D is incorrect as it represents 8 electrons, which is not the correct electron configuration for nitrogen.
5. To the nearest whole number, what is the mass of one mole of hydrogen iodide?
- A. 2 g/mol
- B. 58 g/mol
- C. 87 g/mol
- D. 128 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen iodide (HI) is the sum of the atomic masses of its constituent elements. Hydrogen (H) has a molar mass of approximately 1 g/mol, and iodine (I) has a molar mass of about 127 g/mol. Thus, the molar mass of hydrogen iodide (HI) is approximately 1 + 127 = 128 g/mol. Rounding to the nearest whole number, the molar mass of hydrogen iodide is 128 g/mol, which is closest to choice C. Choice A (2 g/mol) is too low and does not reflect the correct molar mass of hydrogen iodide. Choice B (58 g/mol) is significantly lower than the actual molar mass. Choice D (128 g/mol) matches the calculated molar mass but is not the nearest whole number as requested.
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