HESI A2
HESI A2 Chemistry Practice Questions
1. Which element has an atomic mass greater than that of sodium?
- A. Boron
- B. Oxygen
- C. Fluorine
- D. Silicon
Correct answer: D
Rationale: Silicon has an atomic mass greater than that of sodium. The atomic mass of silicon is approximately 28.0855 u, whereas the atomic mass of sodium is approximately 22.9898 u. Therefore, silicon has a greater atomic mass compared to sodium. Boron, Oxygen, and Fluorine have atomic masses lower than sodium, making them incorrect choices in this context.
2. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
3. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
4. To the nearest whole number, what is the mass of one mole of sodium chloride?
- A. 36 g/mol
- B. 43 g/mol
- C. 58 g/mol
- D. 72 g/mol
Correct answer: C
Rationale: The molar mass of sodium chloride (NaCl) is calculated by adding the atomic masses of sodium (Na) and chlorine (Cl). The atomic mass of sodium is approximately 23 g/mol and chlorine is approximately 35.5 g/mol. Adding these two atomic masses gives us a molar mass of approximately 58 g/mol for sodium chloride (NaCl). Therefore, the correct answer is C, 58 g/mol. Choice A (36 g/mol) is incorrect as it does not account for the individual atomic masses of sodium and chlorine. Choice B (43 g/mol) and choice D (72 g/mol) are also incorrect as they do not reflect the accurate molar mass of sodium chloride.
5. What term refers to the average of the masses of each of its isotopes as they occur in nature?
- A. Atomic number
- B. Mass number
- C. Atomic mass
- D. Neutron number
Correct answer: C
Rationale: The correct answer is atomic mass. Atomic mass is the weighted average of the masses of an element's isotopes. It takes into account the abundance of each isotope in nature to provide a more accurate representation of the element's overall mass. Choice A, atomic number, represents the number of protons in an atom. Choice B, mass number, refers to the total number of protons and neutrons in an atom's nucleus. Choice D, neutron number, specifically focuses on the count of neutrons in an atom's nucleus. These choices do not directly relate to the average mass of isotopes as asked in the question.
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