which element has an atomic mass greater than that of sodium
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HESI A2

HESI A2 Chemistry Practice Questions

1. Which element has an atomic mass greater than that of sodium?

Correct answer: D

Rationale: Silicon has an atomic mass greater than that of sodium. The atomic mass of silicon is approximately 28.0855 u, whereas the atomic mass of sodium is approximately 22.9898 u. Therefore, silicon has a greater atomic mass compared to sodium. Boron, Oxygen, and Fluorine have atomic masses lower than sodium, making them incorrect choices in this context.

2. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?

Correct answer: A

Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.

3. Which of these types of intermolecular force is weakest?

Correct answer: B

Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.

4. On the periodic table, where are atoms with the largest atomic radius located?

Correct answer: C

Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.

5. What distinguishes one allotrope from another?

Correct answer: A

Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.

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