HESI A2
HESI A2 Chemistry Questions
1. How can water be boiled at room temperature?
- A. By lowering the pressure
- B. By increasing the pressure
- C. By decreasing the volume
- D. By raising the boiling point
Correct answer: A
Rationale: The boiling point of water is directly affected by pressure. By lowering the pressure, water can boil at a lower temperature, even at room temperature. This occurs because at lower pressures, the molecules of water have less resistance to escaping into the vapor phase, thus enabling boiling to occur at lower temperatures. Choices B, C, and D are incorrect because increasing the pressure, decreasing the volume, or raising the boiling point would actually require higher temperatures to boil water rather than achieving boiling at room temperature.
2. Which of the following types of matter changes in volume with changes in temperature and pressure?
- A. Liquid
- B. Gas
- C. Solid
- D. Plasma
Correct answer: B
Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.
3. What is the pH of a neutral solution?
- A. 7
- B. 0
- C. 14
- D. 4
Correct answer: A
Rationale: The correct answer is A: 7. A neutral solution has a pH of 7. In the pH scale, values below 7 are acidic, 7 is neutral, and values above 7 are basic. Therefore, a solution with a pH of 7 is considered neutral as it is neither acidic nor basic. Choices B, C, and D are incorrect because a pH of 0 indicates a strong acid, a pH of 14 indicates a strong base, and a pH of 4 indicates an acidic solution. None of these values represent a neutral solution.
4. Which type of chemical reaction involves two ionic compounds where the reactants yield 'switched partners'?
- A. Single replacement
- B. Double replacement
- C. Synthesis
- D. Decomposition
Correct answer: B
Rationale: The correct answer is 'Double replacement.' In a double replacement reaction, two ionic compounds react by exchanging ions, resulting in the formation of two new compounds where the positive and negative ions have 'switched partners.' This type of reaction is characterized by the exchange of ions between the reactants. Choice A, 'Single replacement,' involves an element replacing another in a compound, not the exchange of partners like in the given scenario. Choice C, 'Synthesis,' is the combination of two or more substances to form a more complex product, not involving the exchange of partners. Choice D, 'Decomposition,' is the breakdown of a compound into simpler substances, which is different from the scenario described in the question.
5. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
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