HESI A2
HESI A2 Chemistry Questions
1. How can water be boiled at room temperature?
- A. By lowering the pressure
- B. By increasing the pressure
- C. By decreasing the volume
- D. By raising the boiling point
Correct answer: A
Rationale: The boiling point of water is directly affected by pressure. By lowering the pressure, water can boil at a lower temperature, even at room temperature. This occurs because at lower pressures, the molecules of water have less resistance to escaping into the vapor phase, thus enabling boiling to occur at lower temperatures. Choices B, C, and D are incorrect because increasing the pressure, decreasing the volume, or raising the boiling point would actually require higher temperatures to boil water rather than achieving boiling at room temperature.
2. On what concept is Kelvin based?
- A. Freezing point
- B. Absolute zero
- C. Boiling point
- D. Evaporation point
Correct answer: B
Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.
3. To the nearest whole number, what is the mass of one mole of sodium chloride?
- A. 36 g/mol
- B. 43 g/mol
- C. 58 g/mol
- D. 72 g/mol
Correct answer: C
Rationale: The molar mass of sodium chloride (NaCl) is calculated by adding the atomic masses of sodium (Na) and chlorine (Cl). The atomic mass of sodium is approximately 23 g/mol and chlorine is approximately 35.5 g/mol. Adding these two atomic masses gives us a molar mass of approximately 58 g/mol for sodium chloride (NaCl). Therefore, the correct answer is C, 58 g/mol. Choice A (36 g/mol) is incorrect as it does not account for the individual atomic masses of sodium and chlorine. Choice B (43 g/mol) and choice D (72 g/mol) are also incorrect as they do not reflect the accurate molar mass of sodium chloride.
4. What is the correct formula for calcium carbonate?
- A. CaSO₃
- B. CaCO₃
- C. Ca(OH)₂
- D. CH₃OH
Correct answer: B
Rationale: The correct formula for calcium carbonate is CaCO₃, which consists of one calcium (Ca) atom, one carbon (C) atom, and three oxygen (O) atoms. Therefore, choice B, CaCO₃, is the accurate formula for calcium carbonate. Choices A, C, and D do not represent the correct formula for calcium carbonate. Choice A, CaSO₃, is calcium sulfite, not calcium carbonate. Choice C, Ca(OH)₂, is calcium hydroxide, and choice D, CH₃OH, is methanol, none of which are correct formulas for calcium carbonate.
5. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
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