HESI A2
HESI A2 Chemistry
1. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
2. The molar mass of glucose is 180 g/mol. If an IV solution contains 5 g of glucose in 100 g of water, what is the molarity of the solution?
- A. 0.28M
- B. 1.8M
- C. 2.8M
- D. 18M
Correct answer: C
Rationale: To calculate the molarity of the solution, we first need to determine the moles of solute (glucose) and solvent (water) separately. The molar mass of glucose is 180 g/mol. First, calculate the moles of glucose: 5 g / 180 g/mol = 0.02778 mol of glucose. Next, calculate the moles of water: 100 g / 18 g/mol = 5.56 mol of water. Now, calculate the total moles in the solution: 0.02778 mol glucose + 5.56 mol water = 5.5878 mol. Finally, calculate the molarity: Molarity = moles of solute / liters of solution. Since the total mass of the solution is 100 g + 5 g = 105 g = 0.105 kg, which is equal to 0.105 L, the molarity is 5.5878 mol / 0.105 L = 53.22 M, which rounds to 2.8M. Therefore, the correct answer is 2.8M. Choices A, B, and D are incorrect because they do not reflect the accurate molarity calculation based on the moles of solute and volume of the solution.
3. To the nearest whole number, what is the mass of one mole of water?
- A. 16 g/mol
- B. 18 g/mol
- C. 20 g/mol
- D. 22 g/mol
Correct answer: B
Rationale: The molar mass of water (H₂O) is calculated by adding the atomic masses of two hydrogen atoms (each with a molar mass of approximately 1 g/mol) and one oxygen atom (with a molar mass of approximately 16 g/mol). Therefore, the molar mass of water is approximately 18 g/mol, making choice B the correct answer. Choice A (16 g/mol) is incorrect because it represents the molar mass of oxygen, not water. Choices C (20 g/mol) and D (22 g/mol) are incorrect as they do not correspond to the molar mass of water.
4. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
5. What is the charge of a beta particle?
- A. -1
- B. +1
- C. +2
- D. No charge
Correct answer: A
Rationale: A beta particle has a charge of -1. Beta particles are high-energy, high-speed electrons emitted during radioactive decay processes. Since electrons carry a charge of -1, beta particles also carry a charge of -1. This negative charge indicates that beta particles are negatively charged. Option B is incorrect as it suggests a positive charge, which is not the case for beta particles. Option C is incorrect as it indicates a higher positive charge, which is not true for beta particles. Option D is incorrect as beta particles do have a charge, which is negative.
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