HESI A2
HESI A2 Chemistry Practice Test
1. Under which of the following conditions do real gases approach ideal behavior?
- A. At high pressure and high temperature
- B. At low pressure and high temperature
- C. Near the boiling point of water
- D. Real gases can never exhibit ideal behavior
Correct answer: A
Rationale: Real gases approach ideal behavior at high pressure and high temperature. At these conditions, the volume of the gas molecules becomes negligible compared to the total volume of the gas. Additionally, the average distance between molecules becomes small enough for intermolecular forces to become less significant, leading to behavior that closely mirrors the assumptions of the ideal gas law. Choice B is incorrect because low pressure does not favor ideal behavior as the volume of gas molecules becomes more significant. Choice C is incorrect as the boiling point of water does not directly relate to ideal gas behavior. Choice D is incorrect because real gases can approach ideal behavior under specific conditions, such as high pressure and high temperature.
2. Which law states that the pressure of an ideal gas is inversely proportional to its volume, given that the temperature and amount of gas remain constant?
- A. Henry's law
- B. Dalton's law
- C. Brown's law
- D. Boyle's law
Correct answer: D
Rationale: Boyle's law describes the relationship between the pressure and volume of an ideal gas when the temperature and amount of gas are constant. According to Boyle's law, if the pressure of a gas increases, its volume decreases proportionally, and vice versa. This law is expressed by the equation P1V1 = P2V2, where P1 and V1 represent the initial pressure and volume, while P2 and V2 represent the final pressure and volume when the temperature and amount of gas remain unchanged. Understanding Boyle's law is essential in comprehending the behavior of gases under varying conditions and is fundamental in the study of thermodynamics. The other choices are incorrect: - Henry's law deals with the solubility of gases in liquids, not the relationship between pressure and volume of gases. - Dalton's law states that the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of individual gases, not the pressure-volume relationship. - Brown's law is a fabricated concept and does not exist in the context of gas laws.
3. What does the term amphoteric mean?
- A. A substance that only acts as a base
- B. A substance that can act as both a base and an acid
- C. A substance that only acts as an acid
- D. A substance that acts as neither a base nor an acid
Correct answer: B
Rationale: The term 'amphoteric' refers to substances that have the ability to act as both acids and bases depending on the surrounding conditions. This dual nature allows amphoteric substances to donate or accept protons, making them versatile in various chemical reactions. Choice A is incorrect because amphoteric substances can also act as acids. Choice C is incorrect as amphoteric substances can also act as bases. Choice D is incorrect as amphoteric substances can act as either a base or an acid.
4. Which law is expressed by the equation: Ptot = Pa + Pb, where P represents pressure, Ptot is the total pressure, and Pa and Pb are component pressures?
- A. Henry's law
- B. Dalton's law
- C. Boyle's law
- D. Gay-Lussac's law
Correct answer: B
Rationale: The correct answer is B, Dalton's law. Dalton's law states that in a mixture of non-reacting gases, the total pressure is equal to the sum of the partial pressures of the individual gases. The equation Ptot = Pa + Pb represents Dalton's law, where Ptot is the total pressure, and Pa and Pb are the component pressures. Choice A, Henry's law, deals with the solubility of gases in liquids. Choice C, Boyle's law, describes the inverse relationship between the pressure and volume of a gas at constant temperature. Choice D, Gay-Lussac's law, states that the pressure of a gas is directly proportional to its absolute temperature when volume is constant.
5. A molecule of water contains hydrogen and oxygen in a 1:8 ratio by mass. This is a statement of _____.
- A. The law of multiple proportions
- B. The law of conservation of mass
- C. The law of conservation of energy
- D. The law of constant composition
Correct answer: D
Rationale: The statement that a molecule of water contains hydrogen and oxygen in a 1:8 ratio by mass is an example of the law of constant composition. This law states that all samples of a given chemical compound have the same elemental composition. In the case of water (H2O), no matter where you obtain a sample of water, it will always be composed of hydrogen and oxygen in a 1:8 ratio by mass. The law of multiple proportions deals with compounds that can be formed by the combination of elements in different ratios. The law of conservation of mass states that mass is neither created nor destroyed in a chemical reaction. The law of conservation of energy states that energy cannot be created or destroyed, only transferred or converted.
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