HESI A2
HESI A2 Chemistry Practice Test
1. One factor that affects rates of reaction is concentration. Which of these statements about concentration is/are correct?
- A. A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate
- B. A lower concentration of reactants causes fewer effective collisions per unit time, leading to a decreased reaction rate
- C. A higher concentration of reactants causes more effective collisions per unit time, leading to a decreased reaction rate
- D. A higher concentration of reactants causes fewer effective collisions per unit time, leading to an increased reaction rate
Correct answer: A
Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.
2. Under which of the following conditions do real gases approach ideal behavior?
- A. At high pressure and high temperature
- B. At low pressure and high temperature
- C. Near the boiling point of water
- D. Real gases can never exhibit ideal behavior
Correct answer: A
Rationale: Real gases approach ideal behavior at high pressure and high temperature. At these conditions, the volume of the gas molecules becomes negligible compared to the total volume of the gas. Additionally, the average distance between molecules becomes small enough for intermolecular forces to become less significant, leading to behavior that closely mirrors the assumptions of the ideal gas law. Choice B is incorrect because low pressure does not favor ideal behavior as the volume of gas molecules becomes more significant. Choice C is incorrect as the boiling point of water does not directly relate to ideal gas behavior. Choice D is incorrect because real gases can approach ideal behavior under specific conditions, such as high pressure and high temperature.
3. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
4. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?
- A. 4
- B. 6
- C. 8
- D. 10
Correct answer: B
Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.
5. What is the spontaneous, random movement of small particles suspended in a liquid, caused by the unbalanced impacts of molecules on the particle?
- A. Brownian motion
- B. Grey's kinesis
- C. Boyle's wave
- D. None of the above
Correct answer: A
Rationale: Brownian motion is the correct choice as it specifically refers to the spontaneous, random movement of small particles suspended in a liquid, caused by the unbalanced impacts of molecules on the particle. This phenomenon was observed and documented by Robert Brown, leading to the discovery of the existence of molecules. Grey's kinesis and Boyle's wave are not scientifically recognized terms related to this concept.
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