HESI A2
HESI A2 Chemistry
1. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
2. To the nearest whole number, what is the mass of one mole of sodium chloride?
- A. 36 g/mol
- B. 43 g/mol
- C. 58 g/mol
- D. 72 g/mol
Correct answer: C
Rationale: The molar mass of sodium chloride (NaCl) is calculated by adding the atomic masses of sodium (Na) and chlorine (Cl). The atomic mass of sodium is approximately 23 g/mol and chlorine is approximately 35.5 g/mol. Adding these two atomic masses gives us a molar mass of approximately 58 g/mol for sodium chloride (NaCl). Therefore, the correct answer is C, 58 g/mol. Choice A (36 g/mol) is incorrect as it does not account for the individual atomic masses of sodium and chlorine. Choice B (43 g/mol) and choice D (72 g/mol) are also incorrect as they do not reflect the accurate molar mass of sodium chloride.
3. When balanced, the reaction Fe + O₂ → FeO will be?
- A. 2Fe + 2O₂ → 3FeO
- B. 4Fe + 6O₂ → 6FeO
- C. 2Fe + 3O₂ → 2FeO
- D. 4Fe + 3O₂ → 2FeO
Correct answer: C
Rationale: To balance the chemical equation Fe + O₂ → FeO, the coefficients needed are 2 for Fe and 1 for O. Therefore, the balanced equation becomes 2Fe + O₂ → 2FeO, which translates into 2Fe + 3O₂ → 2FeO. This corresponds to option C. Choice A has the incorrect number of oxygen molecules. Choice B has an incorrect number of Fe atoms on the product side. Choice D also has an incorrect number of Fe atoms on the product side.
4. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?
- A. 75 mL
- B. 100 mL
- C. 125 mL
- D. 150 mL
Correct answer: B
Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.
5. What is the correct formula for potassium chloride?
- A. NaCl
- B. KCl
- C. KCl
- D. ClK
Correct answer: B
Rationale: The correct formula for potassium chloride is KCl. In chemical formulas, the symbol for the cation (positive ion) comes first followed by the symbol for the anion (negative ion). Potassium is represented by the symbol K, while chloride is represented by the symbol Cl. Therefore, the formula for potassium chloride is KCl. Choice A (NaCl) is the formula for sodium chloride, not potassium chloride. Choice C is a duplicate of choice B, and choice D (ClK) is an incorrect arrangement of the symbols for potassium and chloride.
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