HESI A2
HESI A2 Chemistry
1. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
2. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
3. What is atomic mass?
- A. Number of protons in an atom
- B. Sum of protons and neutrons
- C. Number of neutrons in an atom
- D. Average weight of an element
Correct answer: B
Rationale: Atomic mass, also known as atomic weight, is the sum of the number of protons and neutrons in an atom. It represents the average mass of an atom of an element, taking into account the different isotopes and their relative abundance. Neutrons contribute to the atomic mass alongside protons, while the number of neutrons alone is not the definition of atomic mass. Choice A is incorrect because it refers only to the number of protons, not the complete atomic mass. Choice C is incorrect as it focuses solely on the number of neutrons, excluding the contribution of protons. Choice D is incorrect as it mentions the 'average weight of an element,' which is related to atomic mass but does not encapsulate the specific definition of atomic mass as the sum of protons and neutrons.
4. What is the correct name of ZnSO₄?
- A. Zinc sulfate
- B. Zinc sulfide
- C. Zinc sulfur
- D. Zinc oxide
Correct answer: A
Rationale: The correct name of ZnSO₄ is zinc sulfate. In this compound, zinc is combined with the polyatomic ion sulfate (SO₄). Sulfate is a common anion formed from sulfur and oxygen atoms. Therefore, the correct name for ZnSO₄ is zinc sulfate. Choice B, Zinc sulfide, is incorrect because sulfide is a different anion (S²⁻) compared to sulfate (SO₄²⁻). Choice C, Zinc sulfur, is incorrect as it does not represent the correct anion in the compound. Choice D, Zinc oxide, is incorrect as it involves an oxygen anion, not sulfate.
5. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
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