HESI A2
HESI A2 Chemistry
1. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?
- A. 75 mL
- B. 100 mL
- C. 125 mL
- D. 150 mL
Correct answer: B
Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.
2. Which of the following is a characteristic of an exothermic reaction?
- A. It absorbs heat
- B. It releases heat
- C. It remains neutral
- D. It requires energy input
Correct answer: B
Rationale: An exothermic reaction is characterized by the release of heat. During an exothermic reaction, energy is released in the form of heat to the surroundings, resulting in a temperature increase. This distinguishes it from endothermic reactions, which absorb heat from the surroundings. Choice A is incorrect because exothermic reactions do not absorb heat; instead, they release heat. Choice C is incorrect as exothermic reactions do not remain neutral; they involve a net release of energy. Choice D is incorrect as exothermic reactions do not require energy input; instead, they release energy.
3. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
4. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
5. At what temperature does water boil in °F?
- A. 210°F
- B. 212°F
- C. 215°F
- D. 220°F
Correct answer: B
Rationale: Water boils at 212°F under standard atmospheric pressure. This is the point at which water changes from a liquid to a gas phase. Choice A (210°F) is incorrect as it is below the boiling point of water. Choice C (215°F) and Choice D (220°F) are also incorrect as they are above the boiling point of water.
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