HESI A2
Chemistry Hesi A2
1. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
2. What charge do Group IIA elements typically have?
- A. 1
- B. +2
- C. -3
- D. 0
Correct answer: B
Rationale: Group IIA elements belong to the alkaline earth metals group in the periodic table. These elements typically have a charge of +2 because they readily lose two electrons to achieve a stable electron configuration. Therefore, the correct answer is B - +2. Choice A (1) is incorrect because Group IIA elements lose two electrons, not one. Choice C (-3) is incorrect because Group IIA elements do not gain electrons to have a negative charge. Choice D (0) is incorrect because Group IIA elements do lose electrons and have a positive charge, not a neutral charge.
3. How does increasing the concentration of reactants affect a chemical reaction?
- A. Decreases the reaction rate
- B. Increases the reaction rate
- C. Stops the reaction
- D. Has no effect
Correct answer: B
Rationale: Increasing the concentration of reactants leads to more reactant particles being available, which, in turn, increases the likelihood of successful collisions between particles. This higher frequency of collisions results in a higher reaction rate. Therefore, option B, 'Increases the reaction rate,' is the correct answer. Choice A, 'Decreases the reaction rate,' is incorrect because higher reactant concentration usually speeds up the reaction. Choice C, 'Stops the reaction,' is incorrect as increasing concentration promotes more collisions, enhancing the reaction. Choice D, 'Has no effect,' is incorrect because changing reactant concentration directly impacts the reaction rate in most cases.
4. What defines a balanced chemical equation?
- A. An equation where the number of atoms of each element is the same on both sides
- B. An equation where there are more products than reactants
- C. An equation where the number of molecules is balanced
- D. An equation with equal masses on both sides
Correct answer: A
Rationale: A balanced chemical equation is one in which the number of atoms of each element is the same on both sides. This balance ensures the law of conservation of mass is upheld, where the total mass of the reactants equals the total mass of the products. Options B, C, and D are incorrect. Option B is incorrect as a balanced equation has an equal number of products and reactants. Option C is incorrect as balancing refers to the number of atoms, not molecules. Option D is incorrect as balancing is based on the number of atoms, not masses. Therefore, option A is the correct choice as it accurately describes a balanced chemical equation.
5. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
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