HESI A2
Chemistry Hesi A2
1. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
2. How does increasing the concentration of reactants affect a chemical reaction?
- A. Decreases the reaction rate
- B. Increases the reaction rate
- C. Stops the reaction
- D. Has no effect
Correct answer: B
Rationale: Increasing the concentration of reactants leads to more reactant particles being available, which, in turn, increases the likelihood of successful collisions between particles. This higher frequency of collisions results in a higher reaction rate. Therefore, option B, 'Increases the reaction rate,' is the correct answer. Choice A, 'Decreases the reaction rate,' is incorrect because higher reactant concentration usually speeds up the reaction. Choice C, 'Stops the reaction,' is incorrect as increasing concentration promotes more collisions, enhancing the reaction. Choice D, 'Has no effect,' is incorrect because changing reactant concentration directly impacts the reaction rate in most cases.
3. What determines polarity in a molecule?
- A. Bond length
- B. Bond strength
- C. Electronegativity
- D. Molecular weight
Correct answer: C
Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.
4. What charge do Group IA elements have?
- A. +1
- B. +2
- C. +3
- D. 0
Correct answer: A
Rationale: Group IA elements, also known as alkali metals, have a +1 charge. They readily lose one electron to achieve a stable electron configuration, forming ions with a single positive charge. This makes +1 the correct choice. Choices B, C, and D are incorrect because alkali metals in Group IA typically lose one electron, so they do not have a +2, +3, or 0 charge.
5. What is the role of a catalyst in a chemical reaction?
- A. Slows down the reaction
- B. Has no effect
- C. Speeds up the reaction
- D. Stops the reaction
Correct answer: C
Rationale: A catalyst speeds up a chemical reaction by lowering the activation energy required for the reaction to occur. It does not get consumed in the reaction and remains unchanged at the end, allowing it to facilitate multiple reaction cycles. Choice A is incorrect because a catalyst actually speeds up the reaction. Choice B is incorrect because catalysts do have an effect by accelerating the reaction. Choice D is incorrect because catalysts do not stop the reaction, but rather increase the reaction rate.
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