HESI A2
Chemistry Hesi A2
1. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
2. Which of the following is not an allotrope of carbon?
- A. Diamond
- B. Graphite
- C. Fluorine
- D. Buckminsterfullerene
Correct answer: C
Rationale: The correct answer is C: Fluorine. Allotropes of carbon are different forms of the same element. Diamonds, graphite, and buckminsterfullerene are all allotropes of carbon. However, fluorine is a separate chemical element and not an allotrope of carbon. Therefore, fluorine does not belong to the group of carbon allotropes.
3. What is the name of the device that separates gaseous ions by their mass-to-charge ratio?
- A. mass spectrometer
- B. interferometer
- C. magnetometer
- D. capacitance meter
Correct answer: A
Rationale: A mass spectrometer is a device specifically designed to separate gaseous ions based on their mass-to-charge ratio. This separation process involves ionization, acceleration of the sample, and the deflection of ions in a magnetic field according to their mass-to-charge ratio. The other options, 'interferometer,' 'magnetometer,' and 'capacitance meter,' do not perform the specific function of separating gaseous ions based on their mass-to-charge ratio, making them incorrect choices.
4. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
5. Which of the following compounds is ionic?
- A. NaCl
- B. H₂O
- C. HCl
- D. NH₃
Correct answer: A
Rationale: The correct answer is NaCl (sodium chloride). Ionic compounds are formed by the transfer of electrons between a metal and a nonmetal. In NaCl, sodium (Na) is a metal, and chlorine (Cl) is a nonmetal. Sodium donates an electron to chlorine, leading to the formation of the ionic bond between them. This results in the formation of an ionic compound, where positively charged sodium ions are attracted to negatively charged chloride ions, creating a crystal lattice structure. Choices B, C, and D are not ionic compounds. H₂O (water) is a covalent compound formed by the sharing of electrons between two nonmetals (oxygen and hydrogen). HCl (hydrogen chloride) and NH₃ (ammonia) are also covalent compounds involving nonmetals sharing electrons, not transferring them.
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