polarity is based on what
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HESI A2

Chemistry HESI A2 Quizlet

1. What determines polarity in a molecule?

Correct answer: C

Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.

2. What is the correct name of ZnSO₄?

Correct answer: A

Rationale: The correct name of ZnSO₄ is zinc sulfate. In this compound, zinc is combined with the polyatomic ion sulfate (SO₄). Sulfate is a common anion formed from sulfur and oxygen atoms. Therefore, the correct name for ZnSO₄ is zinc sulfate. Choice B, Zinc sulfide, is incorrect because sulfide is a different anion (S²⁻) compared to sulfate (SO₄²⁻). Choice C, Zinc sulfur, is incorrect as it does not represent the correct anion in the compound. Choice D, Zinc oxide, is incorrect as it involves an oxygen anion, not sulfate.

3. Which substance shows a decrease in solubility in water with an increase in temperature?

Correct answer: C

Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.

4. What is the oxidation state of the potassium ion in the compound KCl?

Correct answer: A

Rationale: In the compound KCl (potassium chloride), potassium is in Group 1 of the periodic table, which means it has a valence electron of 1. Chlorine is in Group 17 and gains one electron to achieve a stable electron configuration by forming an ionic bond with potassium. As a result, the potassium ion in KCl has a +1 oxidation state. Therefore, the correct answer is +1. Choices B, C, and D are incorrect as they do not reflect the oxidation state of the potassium ion in KCl.

5. Which of the following is a colligative property of a solution?

Correct answer: A

Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.

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