what is the oxidation state of the sulfur atom in sulfuric acid h2so4
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HESI A2

HESI A2 Chemistry Practice Test

1. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?

Correct answer: B

Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.

2. Which of these represents a strong acid?

Correct answer: B

Rationale: Among the options provided, H₂SO₄ (sulfuric acid) represents a strong acid. Strong acids completely ionize in water to produce a high concentration of H+ ions. Sulfuric acid is a strong acid known for its ability to dissociate almost completely in water, making it a strong acid. Choice A, CH₃COOH (acetic acid), is a weak acid that only partially dissociates in water. Choices C and D, NH₃ (ammonia) and KOH (potassium hydroxide), are bases and not acids.

3. How many moles of potassium bromide are in 25 mL of a 4 M KBr solution?

Correct answer: B

Rationale: To find the moles of potassium bromide in 25 mL of a 4 M KBr solution, we first need to convert the volume from milliliters to liters. 25 mL is equal to 0.025 L. Then, we use the formula moles = molarity x volume in liters. Substituting the values, moles = 4 M x 0.025 L = 0.1 mol. Therefore, there are 0.1 moles of KBr in 25 mL of a 4 M solution. Choice A, 0.035 mol, is incorrect as it does not properly calculate the moles. Choice C, 0.18 mol, and choice D, 1.6 mol, are also incorrect as they are not the result of the correct calculation based on the given molarity and volume.

4. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?

Correct answer: B

Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.

5. What are negatively charged ions called?

Correct answer: C

Rationale: Negatively charged ions are called anions. Anions gain electrons and carry a negative charge, which distinguishes them from cations that are positively charged and neutrons and protons that are subatomic particles found in the nucleus of an atom. Choice A, Neutrons, are neutral subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice B, Protons, are positively charged subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice D, Cations, are positively charged ions that lose electrons, which is opposite to the behavior of negatively charged ions.

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