HESI A2
HESI A2 Chemistry
1. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
2. Balance this equation: Zn + HCl → ZnCl + H2.
- A. Zn + 2HCl → ZnCl + H2
- B. Zn + HCl → 2ZnCl + H2
- C. 2Zn + 2HCl → 2ZnCl + H2
- D. Zn + 4HCl → ZnCl + H2
Correct answer: C
Rationale: The given unbalanced equation is Zn + HCl → ZnCl + H2. To balance it, we need to have equal atoms on both sides of the equation. The balanced equation is 2Zn + 2HCl → 2ZnCl + H2. This balanced equation shows that two atoms of Zn combine with two molecules of HCl to form two molecules of ZnCl and one molecule of H2. Choice A is incorrect because it does not balance the equation. Choice B is incorrect as it does not have the same number of atoms on both sides. Choice D is incorrect because it does not balance the equation properly, resulting in an unequal number of atoms on both sides.
3. Which element would you expect to be least reactive?
- A. Li
- B. Cr
- C. Nd
- D. Xe
Correct answer: D
Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.
4. Which of these represents a strong acid?
- A. CH₃COOH
- B. H₂SO₄
- C. NH₃
- D. KOH
Correct answer: B
Rationale: Among the options provided, H₂SO₄ (sulfuric acid) represents a strong acid. Strong acids completely ionize in water to produce a high concentration of H+ ions. Sulfuric acid is a strong acid known for its ability to dissociate almost completely in water, making it a strong acid. Choice A, CH₃COOH (acetic acid), is a weak acid that only partially dissociates in water. Choices C and D, NH₃ (ammonia) and KOH (potassium hydroxide), are bases and not acids.
5. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
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