HESI A2
Chemistry Hesi A2
1. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
2. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
3. What does the mass of one mole of a substance represent?
- A. Atomic mass
- B. Mass number
- C. Molecular weight
- D. Molar mass
Correct answer: D
Rationale: The mass of one mole of a substance is represented by its molar mass. Molar mass is the mass of one mole of a substance and is expressed in grams per mole. It is calculated by summing the atomic masses of all atoms in a molecule. Therefore, the correct answer is D - 'Molar mass'. Choice A, 'Atomic mass', refers to the average mass of an atom of an element. Choice B, 'Mass number', is the total number of protons and neutrons in an atom's nucleus. Choice C, 'Molecular weight', is the average mass of a molecule relative to 1/12 of the mass of an atom of carbon-12.
4. What type of reaction occurs when an acid and a base react to form water and salt?
- A. Neutralization reaction
- B. Decomposition reaction
- C. Combustion reaction
- D. Redox reaction
Correct answer: A
Rationale: A neutralization reaction is the correct answer. In this type of reaction, an acid and a base combine to form water and salt. The acid donates a proton (H+) to the base, forming water, while the remaining ions combine to form a salt. This reaction results in the neutralization of both the acid and the base, hence the name 'neutralization reaction.' Choice B, decomposition reaction, is incorrect because it refers to a reaction where a compound breaks down into simpler substances. Choice C, combustion reaction, is incorrect as it involves a substance reacting with oxygen to produce heat and light. Choice D, redox reaction, is incorrect because it involves the transfer of electrons between reactants.
5. What is a benefit of water's ability to make hydrogen bonds?
- A. Lack of cohesiveness
- B. Low surface tension
- C. Use as a nonpolar solvent
- D. High specific heat
Correct answer: D
Rationale: The correct answer is D, high specific heat. Water's ability to form hydrogen bonds results in a high specific heat capacity, allowing it to absorb and release a large amount of heat energy with minimal temperature change. This property is essential for moderating temperature changes in organisms and maintaining stable environmental conditions for life processes. Choices A, lack of cohesiveness, and C, use as a nonpolar solvent, are incorrect. Water actually has high cohesiveness due to its ability to form hydrogen bonds, and it is a polar solvent, not nonpolar. Choice B, low surface tension, is also incorrect as water's hydrogen bonding contributes to its relatively high surface tension.
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