HESI A2
Chemistry Hesi A2
1. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
2. How many electrons are shared in a single covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: B
Rationale: The correct answer is B: '2'. In a single covalent bond, two electrons are shared between two atoms. Each atom contributes one electron to form the bond, resulting in the sharing of a total of two electrons. Choice A is incorrect because a single covalent bond involves the sharing of two electrons, not one. Choices C and D are incorrect as they do not represent the correct number of electrons shared in a single covalent bond.
3. What is the coefficient of O after the following equation is balanced?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a balanced chemical equation, the coefficient of oxygen (O) in O2 is already 2, so there is no need to adjust its coefficient further. Therefore, the coefficient of O remains as 1. Since the coefficient of O2 is 2, each O atom is represented by the coefficient of 1, and it does not change during the balancing process. Choices B, C, and D are incorrect as they suggest changing the coefficient of oxygen, which is not necessary for O2 in a balanced equation.
4. Which of these elements has the greatest atomic mass?
- A. Au
- B. Ba
- C. I
- D. W
Correct answer: D
Rationale: Among the elements listed, Tungsten (W) has the greatest atomic mass. The atomic mass of Tungsten is approximately 183.84 atomic mass units (amu), while the atomic masses of the other elements listed are as follows: Gold (Au) is around 196.97 amu, Barium (Ba) is approximately 137.33 amu, and Iodine (I) is about 126.90 amu. Therefore, Tungsten (W) has the greatest atomic mass out of the given elements. Gold (Au) has a higher atomic mass than Barium (Ba) and Iodine (I), making choices A, B, and C incorrect.
5. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
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