HESI A2
Chemistry Hesi A2
1. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
2. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
3. What determines polarity in a molecule?
- A. Bond length
- B. Bond strength
- C. Electronegativity
- D. Molecular weight
Correct answer: C
Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.
4. Which type of chemical reaction involves an active metal reacting with an ionic compound to create a new compound?
- A. Combustion
- B. Single replacement
- C. Synthesis
- D. Decomposition
Correct answer: B
Rationale: The correct answer is 'Single replacement.' In a single replacement reaction, an active metal replaces another element in an ionic compound, resulting in the formation of a new compound. Option A, 'Combustion,' involves a substance rapidly reacting with oxygen to release energy in the form of heat and light. Option C, 'Synthesis,' involves the combination of two or more substances to form a more complex product. Option D, 'Decomposition,' involves the breakdown of a compound into simpler substances.
5. What are neutral particles called?
- A. Neutrons
- B. Protons
- C. Electrons
- D. Cations
Correct answer: A
Rationale: Neutral particles, which have no electric charge, are known as neutrons. Neutrons are found in the nucleus of an atom along with protons. Electrons carry a negative charge and orbit the nucleus. Cations are positively charged ions formed by losing electrons. Therefore, the correct answer is 'Neutrons' as they are the neutral particles in an atom, unlike protons, electrons, or cations.
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