HESI A2
HESI A2 Chemistry Questions
1. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
2. What does the sum of protons and neutrons in an element represent?
- A. Atomic number
- B. Mass number
- C. Atomic mass
- D. Neutron number
Correct answer: B
Rationale: The sum of protons and neutrons in an element is known as the mass number. The mass number is an important concept in chemistry as it represents the total number of nucleons (protons and neutrons) in an atom's nucleus. It is different from the atomic number, which represents the number of protons in an atom. The atomic mass is the average mass of an element's isotopes, taking into account the abundance of each isotope. Neutron number, on the other hand, specifically refers to the number of neutrons in an atom's nucleus. Therefore, the correct answer is B, mass number.
3. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
4. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
5. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
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