which substance shows a decrease in solubility in water with an increase in temperature
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HESI A2

Chemistry Hesi A2

1. Which substance shows a decrease in solubility in water with an increase in temperature?

Correct answer: C

Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.

2. Which two elements are most alike in reactivity?

Correct answer: C

Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.

3. What is atomic mass?

Correct answer: B

Rationale: Atomic mass, also known as atomic weight, is the sum of the number of protons and neutrons in an atom. It represents the average mass of an atom of an element, taking into account the different isotopes and their relative abundance. Neutrons contribute to the atomic mass alongside protons, while the number of neutrons alone is not the definition of atomic mass. Choice A is incorrect because it refers only to the number of protons, not the complete atomic mass. Choice C is incorrect as it focuses solely on the number of neutrons, excluding the contribution of protons. Choice D is incorrect as it mentions the 'average weight of an element,' which is related to atomic mass but does not encapsulate the specific definition of atomic mass as the sum of protons and neutrons.

4. What is 119 K in degrees Celsius?

Correct answer: B

Rationale: To convert Kelvin (K) to Celsius (°C), you subtract 273.15 from the Kelvin value. Therefore, 119 K - 273.15 = -154.15°C. The negative sign indicates that the temperature is below freezing. When rounded to the nearest whole number, -154.15°C is approximately -154°C. Choice A and Choice C are incorrect as they do not reflect the correct conversion from Kelvin to Celsius. Choice D is incorrect as it corresponds to the freezing point of water in Celsius, not the conversion of 119 K.

5. What is the primary function of enzymes?

Correct answer: B

Rationale: Enzymes function to speed up reactions by lowering the activation energy required for the reaction to occur. They act as biological catalysts, providing an alternative pathway for the reaction to proceed more rapidly without being consumed in the process. Choices A, C, and D are incorrect because enzymes do not provide energy for reactions (they do not generate energy), their primary function is not to decrease activation energy (though they do lower it), and while they act as catalysts, the primary function is to speed up reactions by lowering activation energy.

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