HESI A2
Chemistry Hesi A2
1. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
2. How many electron pairs are shared to form a double covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: B
Rationale: The correct answer is B. In a double covalent bond, two pairs of electrons are shared between two atoms. This sharing of two electron pairs results in a stronger bond compared to a single covalent bond where only one pair of electrons is shared. Choice A is incorrect because a single covalent bond involves the sharing of one pair of electrons. Choices C and D are incorrect as they do not represent the correct number of electron pairs shared in a double covalent bond.
3. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
4. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
5. What is stoichiometry?
- A. The study of energy changes in chemical reactions
- B. The study of the mass relationships in chemical reactions
- C. The study of atomic structure
- D. The study of molecular geometry
Correct answer: B
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.
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