HESI A2
Chemistry Hesi A2
1. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
2. What is the main component of air?
- A. Oxygen
- B. Nitrogen
- C. Carbon dioxide
- D. Argon
Correct answer: B
Rationale: Nitrogen is the main component of air, constituting approximately 78% of the Earth's atmosphere. Oxygen, carbon dioxide, and argon are also present in smaller amounts, but nitrogen is the most abundant gas in the air. Therefore, the correct answer is B. Choice A, oxygen, is essential for respiration but makes up only about 21% of the atmosphere. Choice C, carbon dioxide, is vital for photosynthesis but exists in trace amounts in the air. Choice D, argon, is a noble gas found in relatively small quantities in the atmosphere.
3. What type of intermolecular force is a dipole attraction?
- A. Strong
- B. Weak
- C. Medium
- D. Very strong
Correct answer: B
Rationale: A dipole attraction is considered a weak intermolecular force. It occurs between molecules with permanent dipoles, where the positive end of one molecule is attracted to the negative end of another molecule. While dipole-dipole interactions are stronger than dispersion forces, they are weaker than hydrogen bonding or ion-dipole interactions. Therefore, the correct answer is 'Weak.' Choices A, C, and D are incorrect because dipole attractions are not classified as strong, medium, or very strong intermolecular forces, but rather fall into the category of weak intermolecular forces.
4. How many moles of potassium bromide are in 25 mL of a 4 M KBr solution?
- A. 0.035 mol
- B. 0.1 mol
- C. 0.18 mol
- D. 1.6 mol
Correct answer: B
Rationale: To find the moles of potassium bromide in 25 mL of a 4 M KBr solution, we first need to convert the volume from milliliters to liters. 25 mL is equal to 0.025 L. Then, we use the formula moles = molarity x volume in liters. Substituting the values, moles = 4 M x 0.025 L = 0.1 mol. Therefore, there are 0.1 moles of KBr in 25 mL of a 4 M solution. Choice A, 0.035 mol, is incorrect as it does not properly calculate the moles. Choice C, 0.18 mol, and choice D, 1.6 mol, are also incorrect as they are not the result of the correct calculation based on the given molarity and volume.
5. What is 0 K equal to in °C?
- A. -300°C
- B. -273°C
- C. -250°C
- D. -200°C
Correct answer: B
Rationale: 0 Kelvin, also known as absolute zero, is equal to -273°C. This is the point at which all molecular motion stops, making it the lowest possible temperature on the Kelvin scale. Choice A (-300°C) is incorrect as it is not the correct conversion of 0 K to °C. Choice C (-250°C) and Choice D (-200°C) are also incorrect as they do not correspond to the accurate conversion of 0 K to °C.
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