HESI A2
HESI A2 Chemistry
1. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
2. What is the correct formula for iron III oxide?
- A. IO
- B. FeS
- C. Fe₂O₃
- D. OFe₂₃
Correct answer: C
Rationale: The correct formula for iron III oxide is Fe2O3. In this formula, Fe represents iron and O represents oxygen. Iron III oxide consists of two iron (Fe) ions combined with three oxygen (O) ions. Thus, the correct formula is Fe2O3. Choice A (IO) is incorrect as it does not represent the correct combination of iron and oxygen ions. Choice B (FeS) is incorrect as it represents iron sulfide, not iron III oxide. Choice D (OFe₂₃) is incorrect as it does not follow the correct chemical nomenclature for iron III oxide.
3. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
4. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
5. What is the simplest form of a substance that is represented by a letter or letters?
- A. Compound
- B. Mixture
- C. Element
- D. Molecule
Correct answer: C
Rationale: The correct answer is C, 'Element.' An element is the most basic form of a substance that cannot be broken down further by chemical reactions. Each element is represented by a unique symbol, typically consisting of one or two letters. Choice A, 'Compound,' is incorrect as compounds are formed by the combination of two or more elements. Choice B, 'Mixture,' is also incorrect as mixtures are composed of two or more substances physically combined. Choice D, 'Molecule,' refers to the smallest unit of a compound that retains the chemical properties of that compound, not the simplest form of a substance represented by a symbol.
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