HESI A2
HESI A2 Chemistry
1. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
2. Which substance has a pH value greater than 7?
- A. Water
- B. Vinegar
- C. Lemon juice
- D. Baking soda
Correct answer: D
Rationale: The correct answer is D, Baking soda. Baking soda has a pH greater than 7, making it basic. pH values above 7 indicate alkalinity, and baking soda, being a base, has a pH higher than 7. Water, vinegar, and lemon juice have pH values below 7, indicating acidity. Water is neutral with a pH of 7, while vinegar and lemon juice are acidic with pH values lower than 7.
3. In the solid state, you would expect a nonmetal to be _________.
- A. brittle
- B. lustrous
- C. malleable
- D. conductive
Correct answer: A
Rationale: In the solid state, you would expect a nonmetal to be brittle. Nonmetals generally lack the malleability and ductility of metals, which makes them prone to being brittle and easily fractured under stress. This property is due to the lack of metallic bonding in nonmetals, which results in a more rigid and less flexible structure. Choice B, 'lustrous,' is incorrect because nonmetals typically do not exhibit a shiny or reflective surface like metals do. Choice C, 'malleable,' is also incorrect as nonmetals lack the ability to be hammered or rolled into thin sheets like metals. Choice D, 'conductive,' is incorrect since nonmetals are generally poor conductors of electricity compared to metals.
4. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
5. What is the correct formula for iron III oxide?
- A. IO
- B. FeS
- C. Fe₂O₃
- D. OFe₂₃
Correct answer: C
Rationale: The correct formula for iron III oxide is Fe2O3. In this formula, Fe represents iron and O represents oxygen. Iron III oxide consists of two iron (Fe) ions combined with three oxygen (O) ions. Thus, the correct formula is Fe2O3. Choice A (IO) is incorrect as it does not represent the correct combination of iron and oxygen ions. Choice B (FeS) is incorrect as it represents iron sulfide, not iron III oxide. Choice D (OFe₂₃) is incorrect as it does not follow the correct chemical nomenclature for iron III oxide.
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