HESI A2
HESI A2 Chemistry
1. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
2. Arsenic and silicon are examples of ___________.
- A. metals
- B. nonmetals
- C. metalloids
- D. heavy metals
Correct answer: C
Rationale: Arsenic and silicon are both examples of metalloids. Metalloids have properties that lie between those of metals and nonmetals. They exhibit characteristics of both groups, making them versatile elements with various applications in different industries. Choice A (metals) is incorrect as arsenic and silicon do not exhibit typical metallic properties. Choice B (nonmetals) is incorrect as they do not possess all the properties of nonmetals. Choice D (heavy metals) is incorrect as heavy metals refer to a different group of elements with high atomic weights, and arsenic and silicon are not categorized as heavy metals.
3. What are the products of combustion of a hydrocarbon in excess oxygen?
- A. Carbon dioxide and water
- B. Naphthalene
- C. Chlorine and bromine
- D. Carbonium ions
Correct answer: A
Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.
4. What is the name of the bond formed when two atoms share electrons?
- A. Covalent bond
- B. Ionic bond
- C. Metallic bond
- D. Hydrogen bond
Correct answer: A
Rationale: A covalent bond is formed when two atoms share electrons, creating a stable electron configuration. This sharing allows both atoms to achieve a full outer shell of electrons, leading to a stable molecule. In contrast, an ionic bond involves the transfer of electrons from one atom to another, resulting in the formation of ions with opposite charges. Metallic bonds are formed between metal atoms and involve a 'sea of electrons' that are delocalized and free to move. Hydrogen bonds are a type of intermolecular force, not a true chemical bond, and occur between a hydrogen atom and a highly electronegative atom like oxygen or nitrogen.
5. In what type of covalent compounds are dispersion forces typically found?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces that occur in non-polar covalent compounds. These forces result from temporary shifts in electron density within molecules, creating temporary dipoles. As a result, non-polar molecules, which lack a permanent dipole moment, can experience these dispersion forces. Polar compounds exhibit stronger intermolecular forces such as dipole-dipole interactions or hydrogen bonding, while ionic compounds involve electrostatic interactions between ions. Therefore, the correct answer is non-polar (choice B). Choices A, C, and D are incorrect because dispersion forces are typically found in non-polar covalent compounds, not polar, ionic, or hydrogen-bonded compounds.
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