HESI A2
Chemistry HESI A2 Quizlet
1. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
2. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
3. Which number represents the number of protons in an element?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Proton number
Correct answer: C
Rationale: The correct answer is C: Atomic number. The atomic number corresponds to the number of protons in an element. Protons are positively charged subatomic particles found in the nucleus of an atom. Each element has a unique atomic number, which defines its identity based on the number of protons it contains. Choice A, Atomic mass, is incorrect as it refers to the average mass of an atom of an element. Choice B, Mass number, represents the total number of protons and neutrons in an atom's nucleus. Choice D, Proton number, is not a commonly used term in chemistry to indicate the number of protons.
4. What are the 3 types of radiation in nuclear chemistry?
- A. Alpha, Beta, Delta
- B. Alpha, Beta, Gamma
- C. Gamma, Beta, Delta
- D. Delta, Beta, Gamma
Correct answer: B
Rationale: The correct answer is B: Alpha, Beta, Gamma. In nuclear chemistry, the 3 types of radiation are alpha, beta, and gamma radiation. Alpha radiation consists of helium nuclei, beta radiation involves electrons or positrons, and gamma radiation is electromagnetic radiation of high frequency. Choice A is incorrect because 'Delta' is not a type of radiation in nuclear chemistry. Choice C is incorrect as it does not list alpha radiation. Choice D is incorrect as it lists the types in the wrong order and includes 'Delta' instead of alpha radiation.
5. What happens in a single displacement reaction?
- A. A compound decomposes into two substances.
- B. An active element displaces a less active element.
- C. A precipitate solid forms from the reaction of two solutions.
- D. The oxidation states of atoms in the reactants change.
Correct answer: B
Rationale: In a single displacement reaction, an active element displaces a less active element in a compound. This process involves one element replacing another in a compound, resulting in the formation of a new compound. Option A is incorrect because a single displacement reaction does not involve the decomposition of a compound into two substances. Option C is incorrect because it describes a precipitation reaction, not a single displacement reaction. Option D is incorrect because it describes oxidation-reduction reactions, not specifically single displacement reactions.
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