HESI A2
Chemistry Hesi A2
1. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
2. Which of the following elements is the most electronegative?
- A. Oxygen
- B. Fluorine
- C. Nitrogen
- D. Sodium
Correct answer: B
Rationale: Fluorine is the most electronegative element on the periodic table. It has the highest electronegativity value, indicating its strong ability to attract electrons in a chemical bond. This property makes it highly reactive, explaining why it is the correct answer in this question. Oxygen and Nitrogen are also electronegative elements, but they are not as electronegative as Fluorine. Sodium, on the other hand, is not electronegative; it is an electropositive element.
3. Radioactive isotopes are frequently used in medicine. What kind of half-life would a medical isotope probably have?
- A. Seconds-long
- B. Days-long
- C. Years-long
- D. Many years long
Correct answer: B
Rationale: Medical isotopes used in diagnosis and treatment need to have a relatively short half-life to minimize radiation exposure to patients. If the half-life were too long (such as many years) or even years-long, the radiation would persist for too long and could be harmful to the patient. Seconds-long half-lives would not provide enough time for the isotope to be effective. Days-long half-lives strike a balance between providing enough time for the isotope to be used effectively and minimizing radiation exposure.
4. Balance this equation: Zn + HCl → ZnCl + H2.
- A. Zn + 2HCl → ZnCl + H2
- B. Zn + HCl → 2ZnCl + H2
- C. 2Zn + 2HCl → 2ZnCl + H2
- D. Zn + 4HCl → ZnCl + H2
Correct answer: C
Rationale: The given unbalanced equation is Zn + HCl → ZnCl + H2. To balance it, we need to have equal atoms on both sides of the equation. The balanced equation is 2Zn + 2HCl → 2ZnCl + H2. This balanced equation shows that two atoms of Zn combine with two molecules of HCl to form two molecules of ZnCl and one molecule of H2. Choice A is incorrect because it does not balance the equation. Choice B is incorrect as it does not have the same number of atoms on both sides. Choice D is incorrect because it does not balance the equation properly, resulting in an unequal number of atoms on both sides.
5. Which substance has a pH value greater than 7?
- A. Water
- B. Vinegar
- C. Lemon juice
- D. Baking soda
Correct answer: D
Rationale: The correct answer is D, Baking soda. Baking soda has a pH greater than 7, making it basic. pH values above 7 indicate alkalinity, and baking soda, being a base, has a pH higher than 7. Water, vinegar, and lemon juice have pH values below 7, indicating acidity. Water is neutral with a pH of 7, while vinegar and lemon juice are acidic with pH values lower than 7.
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