HESI A2
Chemistry Hesi A2
1. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
2. What is 0 K equal to in °C?
- A. -300°C
- B. -273°C
- C. -250°C
- D. -200°C
Correct answer: B
Rationale: 0 Kelvin, also known as absolute zero, is equal to -273°C. This is the point at which all molecular motion stops, making it the lowest possible temperature on the Kelvin scale. Choice A (-300°C) is incorrect as it is not the correct conversion of 0 K to °C. Choice C (-250°C) and Choice D (-200°C) are also incorrect as they do not correspond to the accurate conversion of 0 K to °C.
3. What is the correct name of AgNO₃?
- A. Argent nitrous
- B. Argent oxide
- C. Silver nitrite
- D. Silver nitrate
Correct answer: D
Rationale: The correct name for AgNO₃ is silver nitrate. In chemical nomenclature, the element symbol Ag represents silver, and the polyatomic ion NO₃ is known as nitrate. Therefore, when the silver ion (Ag⁺) combines with the nitrate ion (NO₃⁻), the resulting compound is named silver nitrate (AgNO₃). Choices A, B, and C are incorrect because they do not accurately represent the composition of AgNO₃. Argent nitrous (Choice A) and Argent oxide (Choice B) do not reflect the correct anion, and Silver nitrite (Choice C) uses a different anion altogether.
4. What determines polarity in a molecule?
- A. Bond length
- B. Bond strength
- C. Electronegativity
- D. Molecular weight
Correct answer: C
Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.
5. What is the product of the decomposition of water?
- A. Hydrogen and oxygen
- B. Carbon dioxide
- C. Nitrogen and hydrogen
- D. Methane
Correct answer: A
Rationale: The correct answer is A: Hydrogen and oxygen. When water undergoes decomposition, it breaks down into hydrogen and oxygen gases through a process known as electrolysis. This reaction is represented by 2H₂O → 2H₂ + O₂. Choice B, carbon dioxide, is incorrect as it is not a product of water decomposition. Choice C, nitrogen and hydrogen, is incorrect as water decomposes into hydrogen and oxygen, not nitrogen. Choice D, methane, is incorrect as methane is not a product of water decomposition.
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