HESI A2
Chemistry HESI A2 Quizlet
1. Which law states that matter can neither be created nor destroyed during a chemical reaction?
- A. Law of Conservation of Energy
- B. Law of Conservation of Mass
- C. Law of Constant Composition
- D. Law of Multiple Proportions
Correct answer: B
Rationale: The correct answer is B, the Law of Conservation of Mass. This law, formulated by Antoine Lavoisier, states that matter cannot be created or destroyed in a chemical reaction. It is a fundamental principle in chemistry that explains the preservation of mass during chemical reactions, indicating that the total mass of the reactants is equal to the total mass of the products. The other choices are incorrect because: A: The Law of Conservation of Energy states that energy cannot be created or destroyed, not matter. C: The Law of Constant Composition refers to compounds having the same composition by mass regardless of their source or how they were prepared, not about the conservation of matter in reactions. D: The Law of Multiple Proportions describes the ratios in which elements combine to form compounds, not the conservation of mass.
2. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
3. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
4. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
5. Al(NO3)3 + H2SO4 → Al2(SO4)3 + HNO3 is an example of which kind of reaction?
- A. Decomposition reaction
- B. Synthesis reaction
- C. Single replacement reaction
- D. Double replacement reaction
Correct answer: C
Rationale: The given chemical equation represents a single replacement reaction. In this reaction, aluminum (Al) displaces hydrogen in sulfuric acid (H2SO4), forming aluminum sulfate (Al2(SO4)3) and releasing nitric acid (HNO3). Single replacement reactions involve an element replacing another element in a compound, which is evident in this reaction. Choice A, Decomposition reaction, is incorrect because decomposition reactions involve a single compound breaking down into two or more substances. Choice B, Synthesis reaction, is incorrect as it involves the combination of two or more substances to form a more complex compound. Choice D, Double replacement reaction, is also incorrect as it involves an exchange of ions between two compounds to form two new compounds.
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