HESI A2
HESI A2 Chemistry
1. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
2. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
3. What is the oxidation state of the oxygen atom in the compound NaOH?
- A. -2
- B. -1
- C. 0
- D. +2
Correct answer: B
Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.
4. What is the charge of noble gases?
- A. -1
- B. 0
- C. 1
- D. 2
Correct answer: B
Rationale: The correct answer is B: 0. Noble gases have a charge of 0 because they have full valence shells and are inert. This makes them stable and unreactive, resulting in a charge of 0 as they do not readily gain or lose electrons. Choices A, C, and D are incorrect because noble gases do not typically form ions by gaining or losing electrons, so they do not carry a charge of -1, 1, or 2.
5. What is the correct name of ZnSO₄?
- A. Zinc sulfate
- B. Zinc sulfide
- C. Zinc sulfur
- D. Zinc oxide
Correct answer: A
Rationale: The correct name of ZnSO₄ is zinc sulfate. In this compound, zinc is combined with the polyatomic ion sulfate (SO₄). Sulfate is a common anion formed from sulfur and oxygen atoms. Therefore, the correct name for ZnSO₄ is zinc sulfate. Choice B, Zinc sulfide, is incorrect because sulfide is a different anion (S²⁻) compared to sulfate (SO₄²⁻). Choice C, Zinc sulfur, is incorrect as it does not represent the correct anion in the compound. Choice D, Zinc oxide, is incorrect as it involves an oxygen anion, not sulfate.
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