HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. Which element is considered a noble gas?
- A. Oxygen
- B. Neon
- C. Hydrogen
- D. Argon
Correct answer: B
Rationale: The correct answer is 'Neon.' Noble gases are a group of elements with very low reactivity. Neon is one of these elements, known for its stable and unreactive nature. Oxygen, hydrogen, and argon do not belong to the noble gas group. Oxygen is a reactive non-metal, hydrogen is a non-metal and the first element in the periodic table, and argon is a noble gas like neon but not the correct answer in this case.
3. How many pairs of electrons are shared between two atoms in a single bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.
4. Which law states that matter can neither be created nor destroyed during a chemical reaction?
- A. Law of Conservation of Energy
- B. Law of Conservation of Mass
- C. Law of Constant Composition
- D. Law of Multiple Proportions
Correct answer: B
Rationale: The correct answer is B, the Law of Conservation of Mass. This law, formulated by Antoine Lavoisier, states that matter cannot be created or destroyed in a chemical reaction. It is a fundamental principle in chemistry that explains the preservation of mass during chemical reactions, indicating that the total mass of the reactants is equal to the total mass of the products. The other choices are incorrect because: A: The Law of Conservation of Energy states that energy cannot be created or destroyed, not matter. C: The Law of Constant Composition refers to compounds having the same composition by mass regardless of their source or how they were prepared, not about the conservation of matter in reactions. D: The Law of Multiple Proportions describes the ratios in which elements combine to form compounds, not the conservation of mass.
5. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?
- A. 0.04 M NaCl
- B. 0.25 M NaCl
- C. 0.40 M NaCl
- D. 2.5 M NaCl
Correct answer: C
Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.
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