HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. Which is a triatomic allotrope of oxygen?
- A. Ozone
- B. Water
- C. Acidic oxide
- D. Carbon dioxide
Correct answer: A
Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.
3. What charge do Group IIA elements typically have?
- A. 1
- B. +2
- C. -3
- D. 0
Correct answer: B
Rationale: Group IIA elements belong to the alkaline earth metals group in the periodic table. These elements typically have a charge of +2 because they readily lose two electrons to achieve a stable electron configuration. Therefore, the correct answer is B - +2. Choice A (1) is incorrect because Group IIA elements lose two electrons, not one. Choice C (-3) is incorrect because Group IIA elements do not gain electrons to have a negative charge. Choice D (0) is incorrect because Group IIA elements do lose electrons and have a positive charge, not a neutral charge.
4. Which material has the smallest specific heat capacity?
- A. water
- B. wood
- C. aluminum
- D. glass
Correct answer: C
Rationale: Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. Among the options provided, aluminum has the smallest specific heat capacity. This means that it requires the least amount of heat to raise its temperature compared to water, wood, and glass. Water has a high specific heat capacity, making it resistant to temperature changes, while wood and glass have higher specific heat capacities compared to aluminum.
5. Which classification best describes B, Si, As, Te, At, Ge, and Sb that form a staircase pattern on the right side of the periodic table?
- A. Metals
- B. Semimetals
- C. Nonmetals
- D. Ultrametals
Correct answer: B
Rationale: B, Si, As, Te, At, Ge, and Sb are located in a staircase pattern on the periodic table's right side. Elements in this region are known as metalloids or semimetals because they exhibit properties of both metals and nonmetals. They possess characteristics of both metallic and non-metallic elements, making them valuable semiconductors with diverse applications in electronics. Choice A is incorrect because these elements are not considered true metals. Choice C is incorrect as these elements do not display typical nonmetal properties exclusively. Choice D, 'Ultrametals,' is not a recognized classification in chemistry and is therefore incorrect.
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