HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
3. What is matter that has a definite shape and volume?
- A. Liquid
- B. Solid
- C. Gas
- D. Plasma
Correct answer: B
Rationale: Matter that has a definite shape and volume is referred to as a solid. Solids maintain their shape and volume under normal conditions, unlike liquids that have a definite volume but take the shape of their container, gases that have neither a definite shape nor volume, and plasma which is a state of matter with no definite shape or volume and consists of charged particles.
4. What are the two types of chemical bonding?
- A. Covalent & hydrogen
- B. Ionic & covalent
- C. Ionic & hydrogen
- D. Covalent & metallic
Correct answer: B
Rationale: The correct answer is B: Ionic & covalent. Ionic bonding involves the transfer of electrons between atoms, resulting in the formation of positive and negative ions attracted to each other. Covalent bonding involves the sharing of electrons between atoms to achieve a stable electron configuration. Choice A is incorrect as hydrogen bonding is a type of intermolecular force, not a primary type of chemical bonding. Choice C is incorrect as hydrogen bonding is not a primary type of chemical bonding. Choice D is incorrect as metallic bonding involves the sharing of electrons in a 'sea of electrons' within a metal lattice, not covalent bonding.
5. What is the correct electron configuration for lithium?
- A. 1s²2s¹
- B. 1s²2s²
- C. 1s²2s¹2p¹
- D. 1s¹2s¹2p²
Correct answer: A
Rationale: The electron configuration for lithium is 1s²2s¹. Lithium has 3 electrons, and the configuration indicates that the first two electrons fill the 1s orbital, while the third electron fills the 2s orbital. Therefore, the correct electron configuration for lithium is 1s²2s¹. Choice B (1s²2s²) is incorrect as it represents the electron configuration for beryllium, not lithium. Choice C (1s²2s¹2p¹) includes the 2p orbital, which is not involved in lithium's electron configuration. Choice D (1s¹2s¹2p²) is incorrect as it does not accurately represent lithium's electron configuration.
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