HESI A2
HESI A2 Chemistry Practice Questions
1. Which one does not name a polar molecule?
- A. NH₃
- B. H₂S
- C. SO₂
- D. CO₂
Correct answer: A
Rationale: The correct answer is NH₃. The molecule NH₃ does not represent a polar molecule because nitrogen and hydrogen in this molecule have a small difference in electronegativity that does not result in a significant polar covalent bond. In contrast, molecules H₂S, SO₂, and CO₂ have polar covalent bonds due to larger electronegativity differences, making them polar molecules. Therefore, options B, C, and D are polar molecules, unlike option A.
2. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
3. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
4. Which chemical reaction involves the formation of a single product from two or more reactants?
- A. Synthesis reaction
- B. Combustion reaction
- C. Decomposition reaction
- D. Double displacement reaction
Correct answer: A
Rationale: A synthesis reaction involves the combination of two or more reactants to form a single product. This type of reaction is characterized by the merging of substances to create a more complex compound. In a synthesis reaction, the reactants bond together to form a new product, making it the correct choice for this scenario. Combustion reactions involve the rapid combination of oxygen with another substance, resulting in the release of energy in the form of heat and light. Decomposition reactions entail the breakdown of a compound into simpler substances, often through the application of heat or electricity. Double displacement reactions involve the exchange of ions between two compounds, leading to the formation of two new compounds.
5. How many pairs of electrons are shared between two atoms in a single bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.
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