HESI A2
HESI A2 Chemistry
1. What is the correct name of ZnSO₄?
- A. Zinc sulfate
- B. Zinc sulfide
- C. Zinc sulfur
- D. Zinc oxide
Correct answer: A
Rationale: The correct name of ZnSO₄ is zinc sulfate. In this compound, zinc is combined with the polyatomic ion sulfate (SO₄). Sulfate is a common anion formed from sulfur and oxygen atoms. Therefore, the correct name for ZnSO₄ is zinc sulfate. Choice B, Zinc sulfide, is incorrect because sulfide is a different anion (S²⁻) compared to sulfate (SO₄²⁻). Choice C, Zinc sulfur, is incorrect as it does not represent the correct anion in the compound. Choice D, Zinc oxide, is incorrect as it involves an oxygen anion, not sulfate.
2. Which chemical reaction involves the breaking of a compound into its components?
- A. Decomposition reaction
- B. Combustion reaction
- C. Neutralization reaction
- D. Single displacement reaction
Correct answer: A
Rationale: The correct answer is A: Decomposition reaction. A decomposition reaction involves breaking down a compound into its components. During this reaction, a single compound breaks down into two or more simpler substances. This process is the opposite of a synthesis reaction where multiple substances combine to form a more complex compound. Choices B, C, and D are incorrect because combustion reaction involves burning a substance in oxygen, neutralization reaction involves the reaction between an acid and a base to form water and a salt, and single displacement reaction involves an element displacing another in a compound.
3. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
4. To the nearest whole number, what is the mass of one mole of water?
- A. 16 g/mol
- B. 18 g/mol
- C. 20 g/mol
- D. 22 g/mol
Correct answer: B
Rationale: The molar mass of water (H₂O) is calculated by adding the atomic masses of two hydrogen atoms (each with a molar mass of approximately 1 g/mol) and one oxygen atom (with a molar mass of approximately 16 g/mol). Therefore, the molar mass of water is approximately 18 g/mol, making choice B the correct answer. Choice A (16 g/mol) is incorrect because it represents the molar mass of oxygen, not water. Choices C (20 g/mol) and D (22 g/mol) are incorrect as they do not correspond to the molar mass of water.
5. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
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