HESI A2
Chemistry Hesi A2
1. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
2. What type of reaction involves atoms attempting to achieve stable electron configurations?
- A. Chemical
- B. Nuclear
- C. Physical
- D. Mechanical
Correct answer: A
Rationale: In a chemical reaction, atoms interact to achieve stable electron configurations through the formation of new chemical bonds or the breaking of existing ones. This process aims to reach a more stable state by filling or emptying electron orbitals, leading to the formation of new substances with more stable configurations. Choice B, nuclear reactions, involve changes in the atomic nucleus rather than electron configurations. Choice C, physical reactions, involve changes in physical state or appearance without changing the chemical makeup. Choice D, mechanical reactions, do not involve the rearrangement of electrons to achieve stable configurations.
3. Which of the following is a characteristic of a chemical change?
- A. Change in shape
- B. Production of gas
- C. Melting
- D. Freezing
Correct answer: B
Rationale: The production of gas is a characteristic of a chemical change. During a chemical change, new substances are formed, often with the release or absorption of energy. The production of gas is a significant indicator of a chemical change because it indicates the formation of new compounds through chemical reactions. Choices A, C, and D are not characteristics of chemical changes. Changes in shape, melting, and freezing are physical changes where the substance's identity remains the same, unlike in chemical changes where new substances with different properties are formed.
4. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
5. To the nearest whole number, what is the mass of one mole of hydrogen iodide?
- A. 2 g/mol
- B. 58 g/mol
- C. 87 g/mol
- D. 128 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen iodide (HI) is the sum of the atomic masses of its constituent elements. Hydrogen (H) has a molar mass of approximately 1 g/mol, and iodine (I) has a molar mass of about 127 g/mol. Thus, the molar mass of hydrogen iodide (HI) is approximately 1 + 127 = 128 g/mol. Rounding to the nearest whole number, the molar mass of hydrogen iodide is 128 g/mol, which is closest to choice C. Choice A (2 g/mol) is too low and does not reflect the correct molar mass of hydrogen iodide. Choice B (58 g/mol) is significantly lower than the actual molar mass. Choice D (128 g/mol) matches the calculated molar mass but is not the nearest whole number as requested.
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