HESI A2
Chemistry Hesi A2
1. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
2. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?
- A. 8
- B. 6
- C. 3
- D. 1.5
Correct answer: C
Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.
3. Which type of change occurs when no change is made to the chemical composition of a substance?
- A. Chemical
- B. Physical
- C. Nuclear
- D. Mechanical
Correct answer: B
Rationale: A physical change refers to alterations in the state of matter without modifying the chemical composition of the substance. Examples of physical changes include changes in state (solid, liquid, gas), shape, size, or phase. In a physical change, the substance may look different or behave differently, but its chemical structure remains the same. On the other hand, chemical changes involve the breaking and forming of chemical bonds, resulting in the creation of entirely new substances with different chemical properties. Nuclear changes involve alterations in the nucleus of an atom, such as radioactive decay. Mechanical changes refer to changes in the position or motion of an object caused by applied forces, like pushing, pulling, or twisting.
4. When balanced, the reaction Fe + O₂ → FeO will be?
- A. 2Fe + 2O₂ → 3FeO
- B. 4Fe + 6O₂ → 6FeO
- C. 2Fe + 3O₂ → 2FeO
- D. 4Fe + 3O₂ → 2FeO
Correct answer: C
Rationale: To balance the chemical equation Fe + O₂ → FeO, the coefficients needed are 2 for Fe and 1 for O. Therefore, the balanced equation becomes 2Fe + O₂ → 2FeO, which translates into 2Fe + 3O₂ → 2FeO. This corresponds to option C. Choice A has the incorrect number of oxygen molecules. Choice B has an incorrect number of Fe atoms on the product side. Choice D also has an incorrect number of Fe atoms on the product side.
5. What is the primary function of enzymes?
- A. To provide energy for reactions
- B. To speed up reactions
- C. To decrease activation energy
- D. To act as a catalyst
Correct answer: B
Rationale: Enzymes function to speed up reactions by lowering the activation energy required for the reaction to occur. They act as biological catalysts, providing an alternative pathway for the reaction to proceed more rapidly without being consumed in the process. Choices A, C, and D are incorrect because enzymes do not provide energy for reactions (they do not generate energy), their primary function is not to decrease activation energy (though they do lower it), and while they act as catalysts, the primary function is to speed up reactions by lowering activation energy.
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