why does fluorine have a higher ionization energy than oxygen

HESI A2

Chemistry Hesi A2

1. Why does fluorine have a higher ionization energy than oxygen?

A. Fluorine has a smaller number of neutrons.
B. Fluorine has a larger number of neutrons.
C. Fluorine has a smaller nuclear charge.
D. Fluorine has a larger nuclear charge.

Correct answer: D

Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.

2. How can the reaction rate of a chemical reaction be increased?

A. Increase the temperature
B. Increase the surface area
C. Increase the concentration of reactants
D. Add a catalyst

Correct answer: A

Rationale: To increase the reaction rate of a chemical reaction, one effective method is to increase the temperature. Raising the temperature provides more energy to the reacting particles, enabling them to collide more frequently and with higher energy, leading to an increase in the reaction rate. While increasing the surface area, concentration of reactants, and adding a catalyst are strategies that can also enhance the reaction rate, raising the temperature has the most direct and immediate impact. Increasing the surface area allows for more contact between reactants, increasing the concentration provides more reactant particles to collide, and adding a catalyst lowers the activation energy required for the reaction to occur. However, these methods may not have as immediate and significant an effect as increasing the temperature.

3. Which of the following is a characteristic of an exothermic reaction?

A. It absorbs heat
B. It releases heat
C. It remains neutral
D. It requires energy input

Correct answer: B

Rationale: An exothermic reaction is characterized by the release of heat. During an exothermic reaction, energy is released in the form of heat to the surroundings, resulting in a temperature increase. This distinguishes it from endothermic reactions, which absorb heat from the surroundings. Choice A is incorrect because exothermic reactions do not absorb heat; instead, they release heat. Choice C is incorrect as exothermic reactions do not remain neutral; they involve a net release of energy. Choice D is incorrect as exothermic reactions do not require energy input; instead, they release energy.

4. On what concept is Kelvin based?

A. Freezing point
B. Absolute zero
C. Boiling point
D. Evaporation point

Correct answer: B

Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.

5. What type of intermolecular force is a dipole attraction?

A. Strong
B. Weak
C. Medium
D. Very strong

Correct answer: B

Rationale: A dipole attraction is considered a weak intermolecular force. It occurs between molecules with permanent dipoles, where the positive end of one molecule is attracted to the negative end of another molecule. While dipole-dipole interactions are stronger than dispersion forces, they are weaker than hydrogen bonding or ion-dipole interactions. Therefore, the correct answer is 'Weak.' Choices A, C, and D are incorrect because dipole attractions are not classified as strong, medium, or very strong intermolecular forces, but rather fall into the category of weak intermolecular forces.