why does fluorine have a higher ionization energy than oxygen

HESI A2

Chemistry Hesi A2

1. Why does fluorine have a higher ionization energy than oxygen?

A. Fluorine has a smaller number of neutrons.
B. Fluorine has a larger number of neutrons.
C. Fluorine has a smaller nuclear charge.
D. Fluorine has a larger nuclear charge.

Correct answer: D

Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.

2. Which of the following is not an allotrope of carbon?

A. Diamond
B. Graphite
C. Fluorine
D. Buckminsterfullerene

Correct answer: C

Rationale: The correct answer is C: Fluorine. Allotropes of carbon are different forms of the same element. Diamonds, graphite, and buckminsterfullerene are all allotropes of carbon. However, fluorine is a separate chemical element and not an allotrope of carbon. Therefore, fluorine does not belong to the group of carbon allotropes.

3. Which law states that matter can neither be created nor destroyed during a chemical reaction?

A. Law of Conservation of Energy
B. Law of Conservation of Mass
C. Law of Constant Composition
D. Law of Multiple Proportions

Correct answer: B

Rationale: The correct answer is B, the Law of Conservation of Mass. This law, formulated by Antoine Lavoisier, states that matter cannot be created or destroyed in a chemical reaction. It is a fundamental principle in chemistry that explains the preservation of mass during chemical reactions, indicating that the total mass of the reactants is equal to the total mass of the products. The other choices are incorrect because: A: The Law of Conservation of Energy states that energy cannot be created or destroyed, not matter. C: The Law of Constant Composition refers to compounds having the same composition by mass regardless of their source or how they were prepared, not about the conservation of matter in reactions. D: The Law of Multiple Proportions describes the ratios in which elements combine to form compounds, not the conservation of mass.

4. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?

A. You will smell Gas A before you smell Gas B.
B. You will smell Gas B before you smell Gas A.
C. You will smell Gas A but not Gas B.
D. You will smell Gas B but not Gas A.

Correct answer: A

Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.

5. What is the name of the process by which a gas turns into a liquid?

A. Sublimation
B. Condensation
C. Evaporation
D. Deposition

Correct answer: B

Rationale: The correct answer is B: Condensation. Condensation is the process where gas transforms into a liquid. When gas cools down, it loses energy and its particles come closer, leading to the formation of liquid droplets. Sublimation is the direct transition from solid to gas without passing through the liquid state. Evaporation is the process of liquid turning into a gas, and deposition is the transition of gas directly into a solid. Therefore, choices A, C, and D are incorrect as they describe different phase transitions.