HESI A2
HESI A2 Chemistry Practice Questions
1. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
2. What is the chemical reaction that involves breaking down a compound into component parts?
- A. Decomposition
- B. Synthesis
- C. Combustion
- D. Single replacement
Correct answer: A
Rationale: Decomposition is the correct answer because in a decomposition reaction, a compound is broken down into simpler substances. This type of reaction involves the splitting of a compound into its component parts, often through the use of heat, light, or electricity. Synthesis (choice B) is the opposite process where simpler substances are combined to form a more complex compound. Combustion (choice C) is a reaction involving rapid oxidation often accompanied by heat and light. Single replacement (choice D) is a reaction where one element replaces another in a compound.
3. Which number represents the number of protons in an element?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Proton number
Correct answer: C
Rationale: The correct answer is C: Atomic number. The atomic number corresponds to the number of protons in an element. Protons are positively charged subatomic particles found in the nucleus of an atom. Each element has a unique atomic number, which defines its identity based on the number of protons it contains. Choice A, Atomic mass, is incorrect as it refers to the average mass of an atom of an element. Choice B, Mass number, represents the total number of protons and neutrons in an atom's nucleus. Choice D, Proton number, is not a commonly used term in chemistry to indicate the number of protons.
4. What is matter that has a definite shape and volume?
- A. Liquid
- B. Solid
- C. Gas
- D. Plasma
Correct answer: B
Rationale: Matter that has a definite shape and volume is referred to as a solid. Solids maintain their shape and volume under normal conditions, unlike liquids that have a definite volume but take the shape of their container, gases that have neither a definite shape nor volume, and plasma which is a state of matter with no definite shape or volume and consists of charged particles.
5. If electrons are not shared equally in a covalent bond, the bond is what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: A
Rationale: A polar covalent bond occurs when electrons are shared unequally between atoms. In this type of bond, one atom has a stronger pull on the shared electrons, leading to a partial positive and partial negative charge distribution within the molecule. Choice B, non-polar, is incorrect because in non-polar covalent bonds, electrons are shared equally between atoms. Choice C, ionic, is incorrect as ionic bonds involve a transfer of electrons rather than sharing. Choice D, hydrogen, is incorrect as it does not describe the nature of a covalent bond.
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