HESI A2
Chemistry HESI A2 Practice Test
1. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
2. Which chemical reaction involves the breaking of a compound into its components?
- A. Decomposition reaction
- B. Combustion reaction
- C. Neutralization reaction
- D. Single displacement reaction
Correct answer: A
Rationale: The correct answer is A: Decomposition reaction. A decomposition reaction involves breaking down a compound into its components. During this reaction, a single compound breaks down into two or more simpler substances. This process is the opposite of a synthesis reaction where multiple substances combine to form a more complex compound. Choices B, C, and D are incorrect because combustion reaction involves burning a substance in oxygen, neutralization reaction involves the reaction between an acid and a base to form water and a salt, and single displacement reaction involves an element displacing another in a compound.
3. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
4. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
5. How are elements arranged in the periodic table?
- A. By their atomic mass
- B. By their chemical properties
- C. By their physical state
- D. By their charge
Correct answer: B
Rationale: Elements are arranged in the periodic table based on their chemical properties, making choice B the correct answer. The periodic table is organized so that elements with similar chemical properties are grouped together in columns, known as groups or families. This arrangement allows for the identification of trends in the behavior of elements and predicting their properties based on their position in the table. Choices A, C, and D are incorrect because the periodic table primarily focuses on the chemical properties of elements, not solely on atomic mass, physical state, or charge.
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