Nursing Elites

1. When the heat of a reaction is negative, which statement is true?

• A. The products have less energy and are less stable.
• B. The products have more energy and are more stable.
• C. The products have less energy and are more stable.
• D. The products have more energy and are less stable.

Correct answer: C

Rationale: When the heat of a reaction is negative, it indicates that the reaction releases energy in the form of heat. This means that the products have lower energy levels compared to the reactants. Lower energy levels are associated with greater stability in chemical systems. Therefore, when the heat of a reaction is negative, the products are more stable due to having less energy than the reactants. Choice A, stating that the products have less energy and are less stable, is incorrect as lower energy levels imply greater stability. Choice B, stating that the products have more energy and are more stable, is incorrect as lower energy levels lead to higher stability. Choice D, stating that the products have more energy and are less stable, is incorrect as lower energy levels are associated with higher stability.

2. Capillarity describes the tendency of fluids to rise or fall in narrow tubes. This phenomenon arises from the interplay of:

• A. Buoyancy and pressure differentials
• B. Density variations and compressibility of the fluid
• C. Viscous dissipation and inertial effects
• D. Surface tension at the liquid-gas interface and intermolecular forces

Correct answer: D

Rationale: Capillarity occurs due to surface tension and intermolecular forces between the liquid and the walls of the narrow tube. These forces cause the liquid to rise or fall depending on the cohesion and adhesion properties. Surface tension at the liquid-gas interface and intermolecular forces are responsible for capillary action, making choice D the correct answer. Choices A, B, and C are incorrect as they do not directly relate to the specific forces involved in capillarity.

3. The Prandtl number (Pr) is a dimensionless property relating:

• A. Viscosity and thermal diffusivity
• B. Density and pressure
• C. Surface tension and pressure
• D. Reynolds number and flow regime

Correct answer: A

Rationale: The Prandtl number (Pr) is a dimensionless number used to characterize fluid flow. It is the ratio of momentum diffusivity to thermal diffusivity. In simpler terms, it relates the ability of a fluid to conduct heat to its ability to conduct momentum. Therefore, the correct relationship is between viscosity and thermal diffusivity, making choice A the correct answer. Choices B, C, and D are incorrect because they do not represent the properties that the Prandtl number relates.

4. Entropy (S) is a thermodynamic property related to the system's disorder. According to the second law of thermodynamics, in a spontaneous process:

• A. The total entropy of the system and surroundings increases.
• B. The total entropy of the system and surroundings decreases.
• C. The total entropy of the system remains constant.
• D. The total entropy of the surroundings increases, while the system's entropy decreases.

Correct answer: A

Rationale: The second law of thermodynamics asserts that the entropy of an isolated system (or the combined system and surroundings) will always increase in a spontaneous process, reflecting an increase in disorder. Therefore, the correct answer is that the total entropy of the system and surroundings increases. Choice B is incorrect because entropy always tends to increase in a spontaneous process, as dictated by the second law of thermodynamics. Choice C is incorrect as entropy typically increases in natural processes. Choice D is incorrect because the second law of thermodynamics states that the total entropy of the system and surroundings always increases in a spontaneous process.

5. A Carnot cycle is a theoretical ideal heat engine operating between two heat reservoirs at different temperatures. Which of the following statements is NOT true about a Carnot cycle?

• A. The efficiency of a Carnot cycle is solely dependent on the absolute temperatures of the hot and cold reservoirs.
• B. It is a reversible cycle, meaning the process can be run in both directions with the same efficiency.
• C. It operates isothermally at the hot and cold reservoir temperatures.
• D. It is the most efficient heat engine operating between the same two reservoir temperatures.

Correct answer: C

Rationale: The statement that is NOT true is C. Although part of the Carnot cycle operates isothermally, not the entire cycle operates isothermally. The Carnot cycle consists of both isothermal and adiabatic processes. Choice A is incorrect because the efficiency of a Carnot cycle is indeed solely dependent on the absolute temperatures of the hot and cold reservoirs. Choice B is correct as a Carnot cycle is reversible, allowing the process to be run in both directions with the same efficiency. Choice D is also true as the Carnot cycle is the most efficient heat engine operating between the same two reservoir temperatures. Therefore, the correct answer is C.

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