HESI A2
Chemistry HESI A2 Quizlet
1. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
2. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
3. Which chemical reaction involves the breaking of a compound into its components?
- A. Decomposition reaction
- B. Combustion reaction
- C. Neutralization reaction
- D. Single displacement reaction
Correct answer: A
Rationale: The correct answer is A: Decomposition reaction. A decomposition reaction involves breaking down a compound into its components. During this reaction, a single compound breaks down into two or more simpler substances. This process is the opposite of a synthesis reaction where multiple substances combine to form a more complex compound. Choices B, C, and D are incorrect because combustion reaction involves burning a substance in oxygen, neutralization reaction involves the reaction between an acid and a base to form water and a salt, and single displacement reaction involves an element displacing another in a compound.
4. What is the correct formula for iron III oxide?
- A. IO
- B. FeS
- C. Fe₂O₃
- D. OFe₂₃
Correct answer: C
Rationale: The correct formula for iron III oxide is Fe2O3. In this formula, Fe represents iron and O represents oxygen. Iron III oxide consists of two iron (Fe) ions combined with three oxygen (O) ions. Thus, the correct formula is Fe2O3. Choice A (IO) is incorrect as it does not represent the correct combination of iron and oxygen ions. Choice B (FeS) is incorrect as it represents iron sulfide, not iron III oxide. Choice D (OFe₂₃) is incorrect as it does not follow the correct chemical nomenclature for iron III oxide.
5. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
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