HESI A2
Chemistry HESI A2 Quizlet
1. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
2. What is the energy required to remove the outermost electron from an atom called?
- A. covalent bonding
- B. electronegativity
- C. atomic radius
- D. ionization energy
Correct answer: D
Rationale: Ionization energy is the energy needed to remove the outermost electron from an atom, resulting in the formation of a positively charged ion. The higher the ionization energy, the more difficult it is to extract an electron. Electronegativity, however, measures an atom's ability to attract shared electrons in a chemical bond. Atomic radius refers to the distance from the nucleus to the outermost electron. Covalent bonding involves sharing electron pairs between atoms to create a stable bond. Therefore, the correct answer is ionization energy as it specifically relates to the energy needed to remove an electron from an atom.
3. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
4. Arsenic and silicon are examples of ___________.
- A. metals
- B. nonmetals
- C. metalloids
- D. heavy metals
Correct answer: C
Rationale: Arsenic and silicon are both examples of metalloids. Metalloids have properties that lie between those of metals and nonmetals. They exhibit characteristics of both groups, making them versatile elements with various applications in different industries. Choice A (metals) is incorrect as arsenic and silicon do not exhibit typical metallic properties. Choice B (nonmetals) is incorrect as they do not possess all the properties of nonmetals. Choice D (heavy metals) is incorrect as heavy metals refer to a different group of elements with high atomic weights, and arsenic and silicon are not categorized as heavy metals.
5. Which of the following elements is a noble gas?
- A. Hydrogen
- B. Fluorine
- C. Argon
- D. Nitrogen
Correct answer: C
Rationale: The correct answer is C: Argon. Argon is a noble gas, part of Group 18 in the periodic table. Noble gases are colorless, odorless, and typically non-reactive under normal conditions. Other elements in this group include helium, neon, krypton, xenon, and radon. Argon finds wide applications in welding, lighting, and scientific research. Choices A, B, and D are not noble gases. Hydrogen is a non-metal, Fluorine is a halogen, and Nitrogen is a diatomic non-metal gas.
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