HESI A2
Chemistry Hesi A2
1. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
- A. 16
- B. 13
- C. 10
- D. 3
Correct answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
2. If electrons are not shared equally in a covalent bond, the bond is what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: A
Rationale: A polar covalent bond occurs when electrons are shared unequally between atoms. In this type of bond, one atom has a stronger pull on the shared electrons, leading to a partial positive and partial negative charge distribution within the molecule. Choice B, non-polar, is incorrect because in non-polar covalent bonds, electrons are shared equally between atoms. Choice C, ionic, is incorrect as ionic bonds involve a transfer of electrons rather than sharing. Choice D, hydrogen, is incorrect as it does not describe the nature of a covalent bond.
3. What happens in a single displacement reaction?
- A. A compound decomposes into two substances.
- B. An active element displaces a less active element.
- C. A precipitate solid forms from the reaction of two solutions.
- D. The oxidation states of atoms in the reactants change.
Correct answer: B
Rationale: In a single displacement reaction, an active element displaces a less active element in a compound. This process involves one element replacing another in a compound, resulting in the formation of a new compound. Option A is incorrect because a single displacement reaction does not involve the decomposition of a compound into two substances. Option C is incorrect because it describes a precipitation reaction, not a single displacement reaction. Option D is incorrect because it describes oxidation-reduction reactions, not specifically single displacement reactions.
4. What is the oxidation state of the oxygen atom in the compound NaOH?
- A. -2
- B. -1
- C. 0
- D. +2
Correct answer: B
Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.
5. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
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