HESI A2
Chemistry Hesi A2
1. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
- A. 16
- B. 13
- C. 10
- D. 3
Correct answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
2. How many electron pairs are shared to form a triple covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: C
Rationale: The correct answer is C. In a triple covalent bond, three pairs of electrons are shared between two atoms. This sharing results in a total of six electrons being shared, making the bond strong. Choice A (1) is incorrect because a single covalent bond involves the sharing of one pair of electrons. Choice B (2) is incorrect as a double covalent bond consists of the sharing of two pairs of electrons. Choice D (4) is incorrect because there are only three pairs of electrons shared in a triple covalent bond, not four.
3. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
4. When balanced, the reaction Fe + O₂ → FeO will be?
- A. 2Fe + 2O₂ → 3FeO
- B. 4Fe + 6O₂ → 6FeO
- C. 2Fe + 3O₂ → 2FeO
- D. 4Fe + 3O₂ → 2FeO
Correct answer: C
Rationale: To balance the chemical equation Fe + O₂ → FeO, the coefficients needed are 2 for Fe and 1 for O. Therefore, the balanced equation becomes 2Fe + O₂ → 2FeO, which translates into 2Fe + 3O₂ → 2FeO. This corresponds to option C. Choice A has the incorrect number of oxygen molecules. Choice B has an incorrect number of Fe atoms on the product side. Choice D also has an incorrect number of Fe atoms on the product side.
5. How many moles of potassium bromide are in 25 mL of a 4 M KBr solution?
- A. 0.035 mol
- B. 0.1 mol
- C. 0.18 mol
- D. 1.6 mol
Correct answer: B
Rationale: To find the moles of potassium bromide in 25 mL of a 4 M KBr solution, we first need to convert the volume from milliliters to liters. 25 mL is equal to 0.025 L. Then, we use the formula moles = molarity x volume in liters. Substituting the values, moles = 4 M x 0.025 L = 0.1 mol. Therefore, there are 0.1 moles of KBr in 25 mL of a 4 M solution. Choice A, 0.035 mol, is incorrect as it does not properly calculate the moles. Choice C, 0.18 mol, and choice D, 1.6 mol, are also incorrect as they are not the result of the correct calculation based on the given molarity and volume.
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