HESI A2
HESI A2 Chemistry Questions
1. What is a benefit of water's ability to make hydrogen bonds?
- A. Lack of cohesiveness
- B. Low surface tension
- C. Use as a nonpolar solvent
- D. High specific heat
Correct answer: D
Rationale: The correct answer is D, high specific heat. Water's ability to form hydrogen bonds results in a high specific heat capacity, allowing it to absorb and release a large amount of heat energy with minimal temperature change. This property is essential for moderating temperature changes in organisms and maintaining stable environmental conditions for life processes. Choices A, lack of cohesiveness, and C, use as a nonpolar solvent, are incorrect. Water actually has high cohesiveness due to its ability to form hydrogen bonds, and it is a polar solvent, not nonpolar. Choice B, low surface tension, is also incorrect as water's hydrogen bonding contributes to its relatively high surface tension.
2. How many pairs of electrons are shared between two atoms in a single bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.
3. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
4. Which of the following elements does not exist as a diatomic molecule?
- A. boron
- B. fluorine
- C. oxygen
- D. nitrogen
Correct answer: A
Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.
5. How many moles of potassium bromide are in 25 mL of a 4 M KBr solution?
- A. 0.035 mol
- B. 0.1 mol
- C. 0.18 mol
- D. 1.6 mol
Correct answer: B
Rationale: To find the moles of potassium bromide in 25 mL of a 4 M KBr solution, we first need to convert the volume from milliliters to liters. 25 mL is equal to 0.025 L. Then, we use the formula moles = molarity x volume in liters. Substituting the values, moles = 4 M x 0.025 L = 0.1 mol. Therefore, there are 0.1 moles of KBr in 25 mL of a 4 M solution. Choice A, 0.035 mol, is incorrect as it does not properly calculate the moles. Choice C, 0.18 mol, and choice D, 1.6 mol, are also incorrect as they are not the result of the correct calculation based on the given molarity and volume.
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