HESI A2
HESI A2 Chemistry Questions
1. What is a benefit of water's ability to make hydrogen bonds?
- A. Lack of cohesiveness
- B. Low surface tension
- C. Use as a nonpolar solvent
- D. High specific heat
Correct answer: D
Rationale: The correct answer is D, high specific heat. Water's ability to form hydrogen bonds results in a high specific heat capacity, allowing it to absorb and release a large amount of heat energy with minimal temperature change. This property is essential for moderating temperature changes in organisms and maintaining stable environmental conditions for life processes. Choices A, lack of cohesiveness, and C, use as a nonpolar solvent, are incorrect. Water actually has high cohesiveness due to its ability to form hydrogen bonds, and it is a polar solvent, not nonpolar. Choice B, low surface tension, is also incorrect as water's hydrogen bonding contributes to its relatively high surface tension.
2. What determines polarity in a molecule?
- A. Bond length
- B. Bond strength
- C. Electronegativity
- D. Molecular weight
Correct answer: C
Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.
3. What is the name of the group of elements that contains chlorine, fluorine, and iodine?
- A. Alkali metals
- B. Halogens
- C. Transition metals
- D. Noble gases
Correct answer: B
Rationale: The correct answer is 'Halogens.' Halogens are a group of elements that include chlorine, fluorine, and iodine. These elements are part of Group 17 in the periodic table. They share similar properties such as high reactivity and the ability to readily form compounds. Choice A, 'Alkali metals,' is incorrect as alkali metals are found in Group 1 of the periodic table, which includes elements like lithium and sodium. Choice C, 'Transition metals,' is incorrect as transition metals are located in the middle section of the periodic table, not in Group 17. Choice D, 'Noble gases,' is incorrect as noble gases are in Group 18 and include elements like helium and neon, which are chemically inert.
4. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
5. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
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