HESI A2
HESI A2 Chemistry
1. What is the oxidation state of the oxygen atom in the compound NaOH?
- A. -2
- B. -1
- C. 0
- D. +2
Correct answer: B
Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.
2. How many times more acidic is a substance with a pH of 3 compared to a substance with a pH of 5?
- A. 8
- B. 2
- C. 100
- D. 1,000
Correct answer: D
Rationale: The pH scale is logarithmic, indicating that each pH unit change reflects a 10-fold difference in acidity level. Going from pH 5 to pH 3 involves a difference of 2 units, which translates to a 100-fold increase in acidity level (10^2 = 100 for each unit). Therefore, a substance with a pH of 3 is 1,000 times more acidic than a substance with a pH of 5 (100 * 10 = 1,000). Choice A (8) is incorrect as it does not consider the logarithmic nature of the pH scale. Choice B (2) is incorrect because it represents the difference in pH units, not the increase in acidity level. Choice C (100) is incorrect as it miscalculates the increase in acidity level, which is 1,000 times and not 100 times.
3. Which of the following represents a hydride ion?
- A. H⁻
- B. H⁺
- C. OH⁻
- D. HCl
Correct answer: A
Rationale: The hydride ion is denoted by H⁻, indicating that it has gained an extra electron to complete its valence shell, resulting in a full octet and a net charge of -1. This ion is commonly found in metal hydrides and plays a significant role in various chemical reactions. Option B, H⁺, represents a proton with a positive charge. Option C, OH⁻, represents the hydroxide ion, consisting of oxygen and hydrogen. Option D, HCl, is a compound composed of hydrogen and chlorine ions, not a hydride ion.
4. What creates a dipole in a covalent bond?
- A. Unequal sharing of electrons
- B. Equal sharing of electrons
- C. Exchange of electrons
- D. Transfer of electrons
Correct answer: A
Rationale: A dipole is created in a covalent bond when there is an unequal sharing of electrons between the atoms involved. This results in a partial positive charge on one atom and a partial negative charge on the other, leading to a separation of charges and the formation of a dipole. Choices B, C, and D are incorrect because a dipole is specifically formed due to unequal sharing of electrons, not equal sharing, exchange, or transfer of electrons in a covalent bond.
5. What are the two types of chemical bonding?
- A. Covalent & hydrogen
- B. Ionic & covalent
- C. Ionic & hydrogen
- D. Covalent & metallic
Correct answer: B
Rationale: The correct answer is B: Ionic & covalent. Ionic bonding involves the transfer of electrons between atoms, resulting in the formation of positive and negative ions attracted to each other. Covalent bonding involves the sharing of electrons between atoms to achieve a stable electron configuration. Choice A is incorrect as hydrogen bonding is a type of intermolecular force, not a primary type of chemical bonding. Choice C is incorrect as hydrogen bonding is not a primary type of chemical bonding. Choice D is incorrect as metallic bonding involves the sharing of electrons in a 'sea of electrons' within a metal lattice, not covalent bonding.
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