HESI A2
HESI A2 Chemistry
1. What are proteins made up of?
- A. Fatty acids
- B. Amino acids
- C. Nucleotides
- D. Sugars
Correct answer: B
Rationale: Proteins are made up of amino acids. Amino acids are the building blocks of proteins, essential for various biological processes in the body such as enzyme function, transport, and structural support. Fatty acids (Choice A) are components of lipids, not proteins. Nucleotides (Choice C) are the building blocks of nucleic acids like DNA and RNA, not proteins. Sugars (Choice D) are carbohydrates and are not the primary components of proteins.
2. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
3. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
4. Which one does not name a polar molecule?
- A. NH₃
- B. H₂S
- C. SO₂
- D. CO₂
Correct answer: A
Rationale: The correct answer is NH₃. The molecule NH₃ does not represent a polar molecule because nitrogen and hydrogen in this molecule have a small difference in electronegativity that does not result in a significant polar covalent bond. In contrast, molecules H₂S, SO₂, and CO₂ have polar covalent bonds due to larger electronegativity differences, making them polar molecules. Therefore, options B, C, and D are polar molecules, unlike option A.
5. Which of the following represents a hydride ion?
- A. H⁻
- B. H⁺
- C. OH⁻
- D. HCl
Correct answer: A
Rationale: The hydride ion is denoted by H⁻, indicating that it has gained an extra electron to complete its valence shell, resulting in a full octet and a net charge of -1. This ion is commonly found in metal hydrides and plays a significant role in various chemical reactions. Option B, H⁺, represents a proton with a positive charge. Option C, OH⁻, represents the hydroxide ion, consisting of oxygen and hydrogen. Option D, HCl, is a compound composed of hydrogen and chlorine ions, not a hydride ion.
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