HESI A2
HESI A2 Chemistry Questions
1. What is the name of the group of elements that contains chlorine, fluorine, and iodine?
- A. Alkali metals
- B. Halogens
- C. Transition metals
- D. Noble gases
Correct answer: B
Rationale: The correct answer is 'Halogens.' Halogens are a group of elements that include chlorine, fluorine, and iodine. These elements are part of Group 17 in the periodic table. They share similar properties such as high reactivity and the ability to readily form compounds. Choice A, 'Alkali metals,' is incorrect as alkali metals are found in Group 1 of the periodic table, which includes elements like lithium and sodium. Choice C, 'Transition metals,' is incorrect as transition metals are located in the middle section of the periodic table, not in Group 17. Choice D, 'Noble gases,' is incorrect as noble gases are in Group 18 and include elements like helium and neon, which are chemically inert.
2. Balance this equation: Fe + Cl2 → FeCl3
- A. 2Fe + 2Cl2 → 2FeCl3
- B. 2Fe + 3Cl2 → 2FeCl3
- C. 3Fe + 2Cl2 → 3FeCl3
- D. 3Fe + 3Cl2 → 6FeCl3
Correct answer: B
Rationale: In the given equation, Fe combines with Cl to form FeCl3. To balance the equation, we need to have the same number of each element on both sides. Since Cl is represented as Cl2 in the equation, we need 3 Cl2 molecules to balance Fe, resulting in 2Fe + 3Cl2 → 2FeCl3. Choice A is incorrect because it only balances Fe but not Cl2. Choice C is incorrect as it balances Fe but not Cl2. Choice D is incorrect as it balances Fe but overbalances Cl2.
3. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
4. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
5. The molar mass of glucose is 180 g/mol. If an IV solution contains 5 g of glucose in 100 g of water, what is the molarity of the solution?
- A. 0.28M
- B. 1.8M
- C. 2.8M
- D. 18M
Correct answer: C
Rationale: To calculate the molarity of the solution, we first need to determine the moles of solute (glucose) and solvent (water) separately. The molar mass of glucose is 180 g/mol. First, calculate the moles of glucose: 5 g / 180 g/mol = 0.02778 mol of glucose. Next, calculate the moles of water: 100 g / 18 g/mol = 5.56 mol of water. Now, calculate the total moles in the solution: 0.02778 mol glucose + 5.56 mol water = 5.5878 mol. Finally, calculate the molarity: Molarity = moles of solute / liters of solution. Since the total mass of the solution is 100 g + 5 g = 105 g = 0.105 kg, which is equal to 0.105 L, the molarity is 5.5878 mol / 0.105 L = 53.22 M, which rounds to 2.8M. Therefore, the correct answer is 2.8M. Choices A, B, and D are incorrect because they do not reflect the accurate molarity calculation based on the moles of solute and volume of the solution.
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