HESI A2
HESI A2 Chemistry Practice Questions
1. What is the correct electron configuration for nitrogen?
- A. 1s² 2s²
- B. 1s² 2s² 2p²
- C. 1s² 2s² 2p³
- D. 1s² 2s² 2p⁴
Correct answer: C
Rationale: The electron configuration of nitrogen is determined by its atomic number, which is 7. Nitrogen has 7 electrons. Following the order of filling orbitals, the electron configuration for nitrogen is 1s² 2s² 2p³. This means the first energy level is filled with 2 electrons in the 1s orbital, the second energy level is filled with 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. Each orbital can hold a specific number of electrons, and nitrogen, with its 7 electrons, fits this configuration. Choice A is incorrect because it does not account for all the electrons in the nitrogen atom. Choice B is incorrect as it only represents 6 electrons, not the 7 electrons in nitrogen. Choice D is incorrect as it represents 8 electrons, which is not the correct electron configuration for nitrogen.
2. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
3. Which element would you expect to be least reactive?
- A. Li
- B. Cr
- C. Nd
- D. Xe
Correct answer: D
Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.
4. What are the three types of intermolecular forces?
- A. Ionic, covalent, hydrogen
- B. Hydrogen bonding, dipole interactions, dispersion forces
- C. Van der Waals, ionic, covalent
- D. Hydrogen, Van der Waals, dispersion forces
Correct answer: B
Rationale: The three types of intermolecular forces are hydrogen bonding, dipole interactions, and dispersion forces. Option A includes ionic and covalent bonds, which are intramolecular forces, not intermolecular. Option C includes van der Waals forces, which encompass dipole interactions and dispersion forces, but also includes ionic and covalent bonds. Option D is close but misses dipole interactions, which are distinct from hydrogen bonding and dispersion forces. Therefore, option B is the correct choice as it includes the three specific types of intermolecular forces.
5. What is another name for aqueous HI?
- A. hydroiodic acid
- B. hydrogen monoiodide
- C. hydrogen iodide
- D. hydriodic acid
Correct answer: D
Rationale: The correct name for aqueous HI is 'hydriodic acid.' When hydrogen iodide (HI) dissolves in water, it forms hydriodic acid. Therefore, 'hydriodic acid' is the appropriate term for aqueous HI. Choice A, 'hydroiodic acid,' is incorrect as it does not reflect the nature of the compound in the aqueous state. Choice B, 'hydrogen monoiodide,' is not a widely recognized term for this compound. Choice C, 'hydrogen iodide,' is the name for HI in the gaseous state, not when it's dissolved in water.
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