HESI A2
HESI A2 Chemistry
1. What type of chemical reaction is represented by AB → A + B?
- A. Synthesis
 - B. Decomposition
 - C. Single replacement
 - D. Double replacement
 
Correct answer: B
Rationale: The chemical equation AB → A + B represents a decomposition reaction. In a decomposition reaction, a single compound breaks down into two or more simpler substances. In this specific reaction, compound AB is decomposed into its elements, A and B, making it a decomposition reaction. Choice A, Synthesis, involves the combination of two or more substances to form a more complex product, which is not the case here. Choices C and D, Single replacement and Double replacement, involve the exchange of ions between compounds or elements, which is not happening in the given reaction.
2. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?
- A. Carbon monoxide
 - B. Helium
 - C. Nitrogen
 - D. Oxygen
 
Correct answer: B
Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.
3. What is matter that has a definite shape and volume?
- A. Liquid
 - B. Solid
 - C. Gas
 - D. Plasma
 
Correct answer: B
Rationale: Matter that has a definite shape and volume is referred to as a solid. Solids maintain their shape and volume under normal conditions, unlike liquids that have a definite volume but take the shape of their container, gases that have neither a definite shape nor volume, and plasma which is a state of matter with no definite shape or volume and consists of charged particles.
4. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
 - B. In the middle of their group
 - C. At the bottom of their group
 - D. Along the right-hand side
 
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
5. Which compound is a Hydrogen or proton donor, corrosive to metals, causes blue litmus paper to become red, and becomes less acidic when mixed with a base?
- A. Base
 - B. Acid
 - C. Salt
 - D. Hydroxide
 
Correct answer: B
Rationale: The correct answer is 'Acid.' An acid is a compound that donates protons (H+), is corrosive to metals, and turns blue litmus paper red. When an acid is mixed with a base, they react to form salts and water, resulting in a decrease in acidity. Choices A, C, and D are incorrect because bases accept protons rather than donate them, salts are the products of acid-base reactions, and hydroxides are typically bases, not acids.
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