HESI A2
Chemistry Hesi A2
1. Identify the type of reaction shown: 8Fe + S → 8FeS
- A. Single displacement
- B. Double displacement
- C. Synthesis
- D. Acid-base
Correct answer: C
Rationale: The reaction shown (8Fe + S → 8FeS) is a synthesis reaction. In a synthesis reaction, two or more substances combine to form a single compound. In this case, iron (Fe) and sulfur (S) combine to form iron sulfide (FeS). The key characteristic of a synthesis reaction is the formation of a single product from multiple reactants, which aligns with the given chemical equation. Choice A, single displacement, involves an element displacing another in a compound, which is not the case here. Choice B, double displacement, involves the exchange of ions between two compounds, which is also not happening in this reaction. Choice D, acid-base, refers to reactions between an acid and a base to form salt and water, which is not the case in the given equation.
2. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
3. What effect does increasing the surface area of a reactant have?
- A. Decreases the reaction rate
- B. Has no effect
- C. Increases the reaction rate
- D. Stops the reaction
Correct answer: C
Rationale: Increasing the surface area of a reactant leads to more particles being exposed to the reaction, which in turn increases the reaction rate. This is because a larger surface area provides more sites for collisions between reacting particles, resulting in a higher frequency of successful collisions and thus accelerating the reaction. Choice A, 'Decreases the reaction rate,' is incorrect because increasing surface area actually accelerates the reaction. Choice B, 'Has no effect,' is incorrect as increasing surface area does have a significant effect on the reaction rate. Choice D, 'Stops the reaction,' is incorrect as increasing surface area does not stop the reaction but rather enhances it.
4. What is a balanced equation?
- A. A description where reactants and products are not equal
- B. An equation where the number of each type of atom is the same on both sides
- C. A chemical formula showing only reactants
- D. An equation without coefficients
Correct answer: B
Rationale: A balanced equation is one where the number of each type of atom is the same on both sides, fulfilling the law of conservation of mass. This principle ensures that the total number of atoms of each element is equal in both reactants and products, signifying that no atoms are created or destroyed, but rather rearranged. Choice A is incorrect because a balanced equation has equal numbers of atoms in the reactants and products. Choice C is incorrect as a balanced equation includes both reactants and products. Choice D is incorrect because coefficients are essential in balancing equations by adjusting the number of atoms present.
5. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
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