b si as te at ge and sb form a staircase pattern on the right side of the periodic table how can these elements be classified

HESI A2

Chemistry HESI A2 Practice Test

1. Which classification best describes B, Si, As, Te, At, Ge, and Sb that form a staircase pattern on the right side of the periodic table?

A. Metals
B. Semimetals
C. Nonmetals
D. Ultrametals

Correct answer: B

Rationale: B, Si, As, Te, At, Ge, and Sb are located in a staircase pattern on the periodic table's right side. Elements in this region are known as metalloids or semimetals because they exhibit properties of both metals and nonmetals. They possess characteristics of both metallic and non-metallic elements, making them valuable semiconductors with diverse applications in electronics. Choice A is incorrect because these elements are not considered true metals. Choice C is incorrect as these elements do not display typical nonmetal properties exclusively. Choice D, 'Ultrametals,' is not a recognized classification in chemistry and is therefore incorrect.

2. What can stop the penetration of alpha particles?

A. Aluminum foil
B. Glass
C. Piece of paper
D. Plastic

Correct answer: C

Rationale: Alpha particles can be stopped by a piece of paper due to their low penetration power. The paper acts as a shield, effectively blocking the alpha particles from passing through. In contrast, materials like aluminum foil, glass, and plastic are not as effective as a simple piece of paper in stopping alpha particles. Aluminum foil is more effective against beta particles, gamma rays, and x-rays due to its higher density. Glass and plastic also provide some protection against beta particles and gamma rays, but they are less effective than a piece of paper against alpha particles.

3. What is the typical oxidation state of oxygen in most compounds?

A. -1
B. -2
C. 0
D. -3

Correct answer: B

Rationale: The correct answer is B: "-2". Oxygen usually exhibits an oxidation state of -2 in most compounds. This is due to oxygen's high electronegativity, which causes it to attract electrons, leading to the gain of two electrons in chemical reactions. Choice A (-1) is incorrect because oxygen rarely has an oxidation state of -1 in compounds. Choice C (0) is incorrect as oxygen does not usually have an oxidation state of zero in compounds. Choice D (-3) is incorrect as oxygen does not commonly have an oxidation state of -3 in compounds.

4. Which compound has a nonpolar bond in which the electrons are shared equally?

A. H₂O
B. NH₃
C. Cl₂
D. CH₄

Correct answer: D

Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.

5. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?

A. You will smell Gas A before you smell Gas B.
B. You will smell Gas B before you smell Gas A.
C. You will smell Gas A but not Gas B.
D. You will smell Gas B but not Gas A.

Correct answer: A

Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.