HESI A2
HESI A2 Chemistry
1. What color does phenolphthalein turn in the presence of an acid?
- A. Clear
- B. Blue
- C. Pink
- D. Red
Correct answer: C
Rationale: In the presence of an acid, phenolphthalein turns pink. Phenolphthalein is a pH indicator that is colorless in acidic solutions but turns pink in basic solutions. Therefore, when added to an acidic solution, phenolphthalein will exhibit a pink coloration. Choice A, 'Clear,' is incorrect because phenolphthalein does not remain colorless in the presence of an acid. Choice B, 'Blue,' is incorrect as phenolphthalein does not turn blue in the presence of an acid. Choice D, 'Red,' is incorrect as phenolphthalein does not exhibit a red color in acidic solutions.
2. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
3. A salt solution has a molarity of 5 M. How many moles of this salt are present in 0 L of this solution?
- A. 0
- B. 1.5
- C. 2
- D. 3
Correct answer: A
Rationale: Molarity is defined as the number of moles of solute per liter of solution. A molarity of 5 M indicates there are 5 moles of salt in 1 liter of the solution. Since the volume of the solution is 0 liters, multiplying the molarity by 0 liters results in 0 moles of salt (5 moles/L x 0 L = 0 moles). Therefore, the correct answer is 0. Option B, 1.5, is incorrect because it doesn't consider the volume being 0 liters. Options C and D, 2 and 3 respectively, are also incorrect as they do not account for the zero volume of the solution. Hence, there are no moles of salt present in 0 liters of the solution.
4. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
5. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?
- A. 75 mL
- B. 100 mL
- C. 125 mL
- D. 150 mL
Correct answer: B
Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.
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