HESI A2
Chemistry HESI A2 Quizlet
1. What effect does increasing the surface area of a reactant have?
- A. Decreases the reaction rate
- B. Has no effect
- C. Increases the reaction rate
- D. Stops the reaction
Correct answer: C
Rationale: Increasing the surface area of a reactant leads to more particles being exposed to the reaction, which in turn increases the reaction rate. This is because a larger surface area provides more sites for collisions between reacting particles, resulting in a higher frequency of successful collisions and thus accelerating the reaction. Choice A, 'Decreases the reaction rate,' is incorrect because increasing surface area actually accelerates the reaction. Choice B, 'Has no effect,' is incorrect as increasing surface area does have a significant effect on the reaction rate. Choice D, 'Stops the reaction,' is incorrect as increasing surface area does not stop the reaction but rather enhances it.
2. What creates a dipole in a covalent bond?
- A. Unequal sharing of electrons
- B. Equal sharing of electrons
- C. Exchange of electrons
- D. Transfer of electrons
Correct answer: A
Rationale: A dipole is created in a covalent bond when there is an unequal sharing of electrons between the atoms involved. This results in a partial positive charge on one atom and a partial negative charge on the other, leading to a separation of charges and the formation of a dipole. Choices B, C, and D are incorrect because a dipole is specifically formed due to unequal sharing of electrons, not equal sharing, exchange, or transfer of electrons in a covalent bond.
3. Cobalt-60 has a half-life of 5 years. If you start with 20 g of cobalt-60, how much is left after 10 years?
- A. 15 g
- B. 10 g
- C. 5 g
- D. 2.5 g
Correct answer: C
Rationale: Cobalt-60's half-life of 5 years means that after 5 years, half of the initial amount remains. Therefore, after 10 years, a quarter (half of a half) of the initial amount will remain. Starting with 20 g, after 10 years, 5 g of cobalt-60 will be left. Choice A (15 g) is incorrect because it assumes a linear decrease, not considering the exponential decay characteristic of radioactive substances. Choice B (10 g) is incorrect as it overlooks that after 10 years, more decay has occurred. Choice D (2.5 g) is incorrect as it represents only an eighth of the initial amount after 10 years, not a quarter.
4. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
5. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
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