HESI A2
Chemistry HESI A2 Practice Test
1. Al(NO3)3 + H2SO4 → Al2(SO4)3 + HNO3 is an example of which kind of reaction?
- A. Decomposition reaction
- B. Synthesis reaction
- C. Single replacement reaction
- D. Double replacement reaction
Correct answer: C
Rationale: The given chemical equation represents a single replacement reaction. In this reaction, aluminum (Al) displaces hydrogen in sulfuric acid (H2SO4), forming aluminum sulfate (Al2(SO4)3) and releasing nitric acid (HNO3). Single replacement reactions involve an element replacing another element in a compound, which is evident in this reaction. Choice A, Decomposition reaction, is incorrect because decomposition reactions involve a single compound breaking down into two or more substances. Choice B, Synthesis reaction, is incorrect as it involves the combination of two or more substances to form a more complex compound. Choice D, Double replacement reaction, is also incorrect as it involves an exchange of ions between two compounds to form two new compounds.
2. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
3. Among the following elements, which is a nonmetal?
- A. Mercury
- B. Magnesium
- C. Sulfur
- D. Potassium
Correct answer: C
Rationale: Sulfur is a nonmetal as it is located on the right side of the periodic table. Nonmetals generally exhibit properties such as being brittle, poor conductors of heat and electricity, and having lower melting points compared to metals. Mercury (A), Magnesium (B), and Potassium (D) are all metals due to their metallic properties. Mercury is a liquid metal at room temperature, Magnesium is a solid metal, and Potassium is a solid metal as well. Therefore, the correct answer is C, Sulfur.
4. What are bases or alkaline solutions known as?
- A. Hydrogen acceptors
- B. Solutions of low pH
- C. Hydrogen donors
- D. Amphoteric
Correct answer: A
Rationale: Bases or alkaline solutions are known as 'hydrogen acceptors.' They accept protons (H+) in chemical reactions, as opposed to acids that donate protons. This property allows bases to neutralize acids and form salts. Choice B, 'Solutions of low pH,' is incorrect because bases have high pH values, not low. Choice C, 'Hydrogen donors,' is incorrect as bases do not donate protons but accept them. Choice D, 'Amphoteric,' refers to substances that can act as both acids and bases, which is not the definition of bases. Therefore, the correct answer is A.
5. Which ion would you expect to dominate in water solutions of bases?
- A. MgCl₂
- B. 2HCl
- C. H⁺
- D. OH⁻
Correct answer: D
Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.
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