HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. What charge do Group IIIA elements have?
- A. +1
- B. +2
- C. +3
- D. 0
Correct answer: C
Rationale: Group IIIA elements, also known as Group 13 elements, have a common oxidation state of +3. This is because they have three valence electrons and tend to lose these electrons to achieve a stable electron configuration, resulting in a +3 charge. Choice A (+1) and Choice B (+2) are incorrect because Group IIIA elements typically lose all three valence electrons to attain a stable configuration, leading to a +3 charge. Choice D (0) is incorrect as these elements do not gain electrons but rather lose them, resulting in a positive charge.
3. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
4. How many pairs of electrons are shared between two atoms in a single bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.
5. What number represents the number of protons an element has?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Neutron number
Correct answer: C
Rationale: The correct answer is C, atomic number. The atomic number corresponds to the number of protons in an element. This number is unique to each element and determines its placement on the periodic table. It is equal to the number of protons found in the nucleus of an atom of that element. Choice A, atomic mass, represents the average mass of an element's isotopes. Choice B, mass number, is the sum of protons and neutrons in an atom. Choice D, neutron number, specifically refers to the count of neutrons in an atom and not protons.
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