HESI A2
Chemistry HESI A2 Practice Test
1. What is the term used when an atom gains one or more electrons?
- A. Cation
- B. Anion
- C. Isotope
- D. Electron
Correct answer: B
Rationale: When an atom gains electrons, it becomes negatively charged and is called an anion. An anion is formed when an atom gains one or more electrons, leading to an excess of negative charge. Choice A, 'Cation,' is incorrect because a cation is formed when an atom loses electrons, resulting in a positively charged ion. Choice C, 'Isotope,' refers to atoms of the same element with different numbers of neutrons and is not related to gaining electrons. Choice D, 'Electron,' is the particle that an atom gains to become an anion, not the term for the atom itself after gaining electrons.
2. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
3. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
4. What is the charge of an alpha particle?
- A. -1
- B. +1
- C. +2
- D. No charge
Correct answer: C
Rationale: An alpha particle consists of two protons and two neutrons, resulting in a total charge of +2 due to the presence of two positively charged protons. Therefore, the correct answer is C, indicating a charge of +2. Choices A, B, and D are incorrect because an alpha particle is positively charged due to the two protons it contains, resulting in a charge of +2.
5. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
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