HESI A2
Chemistry HESI A2 Practice Test
1. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
2. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?
- A. 75 mL
- B. 100 mL
- C. 125 mL
- D. 150 mL
Correct answer: B
Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.
3. What is the correct electron configuration for nitrogen?
- A. 1s² 2s²
- B. 1s² 2s² 2p²
- C. 1s² 2s² 2p³
- D. 1s² 2s² 2p⁴
Correct answer: C
Rationale: The electron configuration of nitrogen is determined by its atomic number, which is 7. Nitrogen has 7 electrons. Following the order of filling orbitals, the electron configuration for nitrogen is 1s² 2s² 2p³. This means the first energy level is filled with 2 electrons in the 1s orbital, the second energy level is filled with 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. Each orbital can hold a specific number of electrons, and nitrogen, with its 7 electrons, fits this configuration. Choice A is incorrect because it does not account for all the electrons in the nitrogen atom. Choice B is incorrect as it only represents 6 electrons, not the 7 electrons in nitrogen. Choice D is incorrect as it represents 8 electrons, which is not the correct electron configuration for nitrogen.
4. Which substance forms hydroxide ions when placed in water?
- A. Lemon juice
- B. Battery acid
- C. Vinegar
- D. Lye
Correct answer: D
Rationale: The correct answer is D, lye. Lye, also known as sodium hydroxide (NaOH), is a strong base that forms hydroxide ions (OH-) when placed in water. When lye dissolves in water, it dissociates into sodium ions (Na+) and hydroxide ions, making it an alkaline substance. Lemon juice, battery acid, and vinegar do not form hydroxide ions when placed in water. Lemon juice contains citric acid, battery acid contains sulfuric acid, and vinegar contains acetic acid, none of which produce hydroxide ions when dissolved in water.
5. Carbon-12 and carbon-14 are isotopes. What do they have in common?
- A. Number of nuclear particles
- B. Number of protons
- C. Number of neutrons
- D. Mass number
Correct answer: C
Rationale: Isotopes are atoms of the same element with the same number of protons (which determines the element) but different numbers of neutrons. Both carbon-12 and carbon-14 have 6 protons (hence they are both carbon atoms) but different numbers of neutrons: carbon-12 has 6 neutrons, while carbon-14 has 8 neutrons. Therefore, the correct answer is the number of neutrons. Choices A, B, and D are incorrect because isotopes may have different numbers of nuclear particles (protons + neutrons), protons, and mass numbers, respectively.
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