what is always different from one allotrope to another
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HESI A2

HESI A2 Chemistry Practice Questions

1. What distinguishes one allotrope from another?

Correct answer: A

Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.

2. Which type of change occurs when no change is made to the chemical composition of a substance?

Correct answer: B

Rationale: A physical change refers to alterations in the state of matter without modifying the chemical composition of the substance. Examples of physical changes include changes in state (solid, liquid, gas), shape, size, or phase. In a physical change, the substance may look different or behave differently, but its chemical structure remains the same. On the other hand, chemical changes involve the breaking and forming of chemical bonds, resulting in the creation of entirely new substances with different chemical properties. Nuclear changes involve alterations in the nucleus of an atom, such as radioactive decay. Mechanical changes refer to changes in the position or motion of an object caused by applied forces, like pushing, pulling, or twisting.

3. What is the correct formula for iron III oxide?

Correct answer: C

Rationale: The correct formula for iron III oxide is Fe2O3. In this formula, Fe represents iron and O represents oxygen. Iron III oxide consists of two iron (Fe) ions combined with three oxygen (O) ions. Thus, the correct formula is Fe2O3. Choice A (IO) is incorrect as it does not represent the correct combination of iron and oxygen ions. Choice B (FeS) is incorrect as it represents iron sulfide, not iron III oxide. Choice D (OFe₂₃) is incorrect as it does not follow the correct chemical nomenclature for iron III oxide.

4. What is the name of the bond formed when two atoms share electrons?

Correct answer: A

Rationale: A covalent bond is formed when two atoms share electrons, creating a stable electron configuration. This sharing allows both atoms to achieve a full outer shell of electrons, leading to a stable molecule. In contrast, an ionic bond involves the transfer of electrons from one atom to another, resulting in the formation of ions with opposite charges. Metallic bonds are formed between metal atoms and involve a 'sea of electrons' that are delocalized and free to move. Hydrogen bonds are a type of intermolecular force, not a true chemical bond, and occur between a hydrogen atom and a highly electronegative atom like oxygen or nitrogen.

5. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?

Correct answer: B

Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.

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