what is kelvin based around
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HESI A2

Chemistry HESI A2 Practice Test

1. On what concept is Kelvin based?

Correct answer: B

Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.

2. To the nearest whole number, what is the mass of one mole of water?

Correct answer: B

Rationale: The molar mass of water (H₂O) is calculated by adding the atomic masses of two hydrogen atoms (each with a molar mass of approximately 1 g/mol) and one oxygen atom (with a molar mass of approximately 16 g/mol). Therefore, the molar mass of water is approximately 18 g/mol, making choice B the correct answer. Choice A (16 g/mol) is incorrect because it represents the molar mass of oxygen, not water. Choices C (20 g/mol) and D (22 g/mol) are incorrect as they do not correspond to the molar mass of water.

3. What is the typical oxidation state of oxygen in most compounds?

Correct answer: B

Rationale: The correct answer is B: "-2". Oxygen usually exhibits an oxidation state of -2 in most compounds. This is due to oxygen's high electronegativity, which causes it to attract electrons, leading to the gain of two electrons in chemical reactions. Choice A (-1) is incorrect because oxygen rarely has an oxidation state of -1 in compounds. Choice C (0) is incorrect as oxygen does not usually have an oxidation state of zero in compounds. Choice D (-3) is incorrect as oxygen does not commonly have an oxidation state of -3 in compounds.

4. What distinguishes one allotrope from another?

Correct answer: A

Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.

5. Which branch of chemistry deals with the quantities and numeric relationships between compounds in a chemical reaction?

Correct answer: A

Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It involves the calculation of quantities of substances consumed and produced in a chemical reaction based on the balanced chemical equation. Choice B, 'Molecular chemistry,' is incorrect as it focuses on the structure, properties, and reactions of molecules. Choice C, 'Atomic chemistry,' is incorrect as it primarily deals with the study of atoms and their interactions. Choice D, 'Thermodynamics,' is incorrect as it pertains to the study of energy and heat transfer in chemical and physical processes.

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