HESI A2
Chemistry HESI A2 Quizlet
1. What charge do Group VIIA elements have?
- A. -1
- B. -2
- C. 0
- D. 1
Correct answer: A
Rationale: Group VIIA elements, also known as halogens, have a tendency to gain one electron to achieve a stable electron configuration, resulting in a -1 charge. This is because they have seven valence electrons and need one more to complete their octet, making them highly reactive in forming -1 ions. Therefore, the correct answer is A. Choice B (-2) is incorrect because Group VIIA elements typically gain one electron, not two. Choice C (0) is incorrect as these elements tend to form -1 ions by gaining one electron. Choice D (1) is incorrect because Group VIIA elements gain electrons to form negative ions, not positive ones.
2. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
3. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
4. How many electron pairs are shared to form a triple covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: C
Rationale: The correct answer is C. In a triple covalent bond, three pairs of electrons are shared between two atoms. This sharing results in a total of six electrons being shared, making the bond strong. Choice A (1) is incorrect because a single covalent bond involves the sharing of one pair of electrons. Choice B (2) is incorrect as a double covalent bond consists of the sharing of two pairs of electrons. Choice D (4) is incorrect because there are only three pairs of electrons shared in a triple covalent bond, not four.
5. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
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