HESI A2
HESI A2 Chemistry
1. Among the following elements, which is a nonmetal?
- A. Mercury
- B. Magnesium
- C. Sulfur
- D. Potassium
Correct answer: C
Rationale: Sulfur is a nonmetal as it is located on the right side of the periodic table. Nonmetals generally exhibit properties such as being brittle, poor conductors of heat and electricity, and having lower melting points compared to metals. Mercury (A), Magnesium (B), and Potassium (D) are all metals due to their metallic properties. Mercury is a liquid metal at room temperature, Magnesium is a solid metal, and Potassium is a solid metal as well. Therefore, the correct answer is C, Sulfur.
2. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
3. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
4. What type of chemical reaction involves the combination of two elements to form a product?
- A. Decomposition
- B. Combustion
- C. Synthesis
- D. Double replacement
Correct answer: C
Rationale: A synthesis reaction involves the combination of two or more substances to form a single, more complex product. In the context of chemical reactions, it specifically refers to the combination of two elements to form a compound. Therefore, the correct answer is C. Decomposition reactions involve the breakdown of a single compound into simpler substances (opposite of synthesis). Combustion reactions involve a substance reacting with oxygen to produce heat and light, not the combination of elements. Double replacement reactions involve the exchange of ions between two compounds, leading to the formation of two new compounds, not the combination of two elements.
5. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
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